Reactivity of metal–oxo clusters towards biomolecules: from discrete polyoxometalates to metal–organic frameworks

DES Marcano, ND Savić, K Declerck… - Chemical Society …, 2024 - pubs.rsc.org
Metal–oxo clusters hold great potential in several fields such as catalysis, materials science,
energy storage, medicine, and biotechnology. These nanoclusters of transition metals with …

Recent progress in the construction and applications of metal-organic frameworks and covalent-organic frameworks-based nanozymes

L Zheng, F Wang, C Jiang, S Ye, J Tong… - Coordination Chemistry …, 2022 - Elsevier
Nanozymes, a kind of catalytic nanomaterials with enzymatic catalytic properties, have
attracted immense interests in recent years owing to their high stability and low cost. Among …

Enhanced Activity of Enzyme Immobilized on Hydrophobic ZIF‐8 Modified by Ni2+ Ions

XG Yang, JR Zhang, XK Tian, JH Qin… - Angewandte …, 2023 - Wiley Online Library
The development of efficient enzyme immobilization to promote their recyclability and activity
is highly desirable. Zeolitic imidazolate framework‐8 (ZIF‐8) has been proved to be an …

Fast Room‐Temperature Synthesis of an Extremely Alkaline‐Resistant Cationic Metal–Organic Framework for Sequestering TcO4 with Exceptional Selectivity

K Kang, S Liu, M Zhang, L Li, C Liu… - Advanced Functional …, 2022 - Wiley Online Library
Leveraging metal–organic framework (MOF) to eliminate radioactive contaminants has
invariably received much attention, but low preparation efficiency and poor selectivity have …

Hydrolase mimic via second coordination sphere engineering in metal-organic frameworks for environmental remediation

X Yuan, X Wu, J **ong, B Yan, R Gao, S Liu… - Nature …, 2023 - nature.com
Enzymes achieve high catalytic activity with their elaborate arrangements of amino acid
residues in confined optimized spaces. Nevertheless, when exposed to complicated …

High peroxidase-mimicking metal–organic frameworks decorated with platinum nanozymes for the colorimetric detection of acetylcholine chloride and …

Y Yi, X Zhou, D Liao, J Hou, H Liu, G Zhu - Inorganic Chemistry, 2023 - ACS Publications
The sensitive detection of acetylcholinesterase (AChE) and organophosphorus pesticides
(OPs) is very important for the protection of human health. Herein, a hybrid material, Pt …

Hydrolytic nanozymes: preparation, properties, and applications

T Chen, Y Lu, X **ong, M Qiu, Y Peng, Z Xu - Advances in Colloid and …, 2024 - Elsevier
Hydrolytic nanozymes, as promising alternatives to hydrolytic enzymes, can efficiently
catalyze the hydrolysis reactions and overcome the operating window limitations of natural …

Nanozyme engineering in structurally explicit framework: Design mechanisms and biosensing applications

Y Xu, A Huang, W Yi, G Chen, S Huang… - Coordination Chemistry …, 2024 - Elsevier
Natural enzymes are crucial catalysts that not only control over the biotransformation in
intracellular environments with high efficiency but also are widely harnessed in vitro for …

Reticular chemistry in its chiral form: axially chiral Zr (IV)-spiro metal–organic framework as a case study

W Gong, X Chen, KM Fahy, J Dong, Y Liu… - Journal of the …, 2023 - ACS Publications
The interplay of primary organic ligands and inorganic secondary building units (SBUs) has
led to a continual boom of reticular chemistry, particularly metal–organic frameworks …

The role of dynamic metal-ligand bonds in metal-organic framework chemistry

JL Obeso, MT Huxley, C Leyva, JG Flores… - Coordination Chemistry …, 2023 - Elsevier
Metal-organic frameworks (MOFs) are an emerging class of porous materials composed of
metal ions or clusters interconnected by organic ligands. Many proposed applications for …