[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …

Facing and overcoming sensitivity challenges in biomolecular NMR spectroscopy

JH Ardenkjaer‐Larsen, GS Boebinger… - Angewandte Chemie …, 2015 - Wiley Online Library
In the Spring of 2013, NMR spectroscopists convened at the Weizmann Institute in Israel to
brainstorm on approaches to improve the sensitivity of NMR experiments, particularly when …

Recent developments in MAS DNP-NMR of materials

AGM Rankin, J Trébosc, F Pourpoint… - Solid State Nuclear …, 2019 - Elsevier
Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …

Theory for cross effect dynamic nuclear polarization under magic-angle spinning in solid state nuclear magnetic resonance: The importance of level crossings

KR Thurber, R Tycko - The Journal of chemical physics, 2012 - pubs.aip.org
We present theoretical calculations of dynamic nuclear polarization (DNP) due to the cross
effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin …

BDPA-nitroxide biradicals tailored for efficient dynamic nuclear polarization enhanced solid-state NMR at magnetic fields up to 21.1 T

D Wisser, G Karthikeyan, A Lund… - Journal of the …, 2018 - ACS Publications
Dynamic nuclear polarization (DNP) solid-state nuclear magnetic resonance (NMR) has
developed into an invaluable tool for the investigation of a wide range of materials …

Instrumentation for solid-state dynamic nuclear polarization with magic angle spinning NMR

M Rosay, M Blank, F Engelke - Journal of Magnetic Resonance, 2016 - Elsevier
Advances in dynamic nuclear polarization (DNP) instrumentation and methodology have
been key factors in the recent growth of solid-state DNP NMR applications. We review the …

A spectrometer designed for 6.7 and 14.1 T DNP-enhanced solid-state MAS NMR using quasi-optical microwave transmission

KJ Pike, TF Kemp, H Takahashi, R Day… - Journal of Magnetic …, 2012 - Elsevier
A Dynamic Nuclear Polarisation (DNP) enhanced solid-state Magic Angle Spinning (MAS)
NMR spectrometer operating at 6.7 T is described and demonstrated. The 187GHz TE13 …

High-field pulsed EPR spectroscopy under magic angle spinning

O Nir-Arad, AB Fialkov, DH Shlomi, N Manukovsky… - Science …, 2024 - science.org
In this work, we demonstrate the first pulsed electron paramagnetic resonance (EPR)
experiments performed under magic angle spinning (MAS) at high magnetic field. Unlike …

THz dynamic nuclear polarization NMR

EA Nanni, AB Barnes, RG Griffin… - IEEE Transactions on …, 2011 - ieeexplore.ieee.org
Dynamic nuclear polarization (DNP) increases the sensitivity of nuclear magnetic resonance
(NMR) spectroscopy by using high frequency microwaves to transfer the polarization of the …

High-field dynamic nuclear polarization

B Corzilius - Annual review of physical chemistry, 2020 - annualreviews.org
Dynamic nuclear polarization (DNP) is one of the most prominent methods of sensitivity
enhancement in nuclear magnetic resonance (NMR). Even though solid-state DNP under …