The role of polysulfide dianions and radical anions in the chemical, physical and biological sciences, including sulfur-based batteries
R Steudel, T Chivers - Chemical Society Reviews, 2019 - pubs.rsc.org
The well-known tendency of sulfur to catenate is exemplified by an extensive series of
polysulfide dianions [Sn] 2−(n= 2–9) and related radical monoanions [Sn]˙−. The dianions …
polysulfide dianions [Sn] 2−(n= 2–9) and related radical monoanions [Sn]˙−. The dianions …
Thermochemical sulfate reduction in sedimentary basins and beyond: A review
C Cai, H Li, K Li, D Wang - Chemical Geology, 2022 - Elsevier
Thermochemical sulfate reduction (TSR) is a set of redox reactions between organic matter
and sulfates at temperatures> 120° C, and occurs in varied environments including deeply …
and sulfates at temperatures> 120° C, and occurs in varied environments including deeply …
Stability and abundance of the trisulfur radical ion S3− in hydrothermal fluids
GS Pokrovski, J Dubessy - Earth and Planetary Science Letters, 2015 - Elsevier
The interpretation of sulfur behavior in geological fluids and melts is based on a long-
standing paradigm that sulfate, sulfide, and sulfur dioxide are the major sulfur compounds …
standing paradigm that sulfate, sulfide, and sulfur dioxide are the major sulfur compounds …
Reaction pathway, mechanism and kinetics of thermochemical sulfate reduction: insights from in situ Raman spectroscopic observations at elevated temperatures and …
Q Wan, X Wang, W Hu, Y Wan, IM Chou - Geochimica et Cosmochimica …, 2024 - Elsevier
In Earth's crust, thermochemical sulfate reduction (TSR) is a common organic–inorganic
interaction, which is in close association with the carbon cycle in sedimentary basins and …
interaction, which is in close association with the carbon cycle in sedimentary basins and …
Study of thermochemical sulfate reduction mechanism using compound specific sulfur isotope analysis
A Meshoulam, GS Ellis, WS Ahmad, A Deev… - … et Cosmochimica Acta, 2016 - Elsevier
The sulfur isotopic fractionation associated with the formation of organic sulfur compounds
(OSCs) during thermochemical sulfate reduction (TSR) was studied using gold-tube …
(OSCs) during thermochemical sulfate reduction (TSR) was studied using gold-tube …
Fluid inclusion evidence for low-temperature thermochemical sulfate reduction (TSR) of dry coal gas in Upper Permian carbonate reservoirs (Zechstein, Ca2) in the …
M Sośnicka, V Lüders - Chemical Geology, 2020 - Elsevier
Abstract Upper Permian Zechstein carbonate Ca2 gas reservoirs in the southern part of the
Pompeckj Block in the North German Basin locally contain up to 36 vol% hydrogen sulfide …
Pompeckj Block in the North German Basin locally contain up to 36 vol% hydrogen sulfide …
Tungsten (VI) speciation in hydrothermal solutions up to 400° C as revealed by in-situ Raman spectroscopy
Tungsten (VI) speciation in hydrothermal solutions is investigated through in-situ Raman
spectroscopy coupled with the fused silica glass capillary technique at temperatures up to …
spectroscopy coupled with the fused silica glass capillary technique at temperatures up to …
Multiple sulfur isotope fractionation and mass transfer processes during pyrite precipitation and recrystallization: An experimental study at 300 and 350° C
DD Syverson, S Ono, WC Shanks… - … et Cosmochimica Acta, 2015 - Elsevier
Equilibrium multiple sulfur isotope fractionation factors (33 S/32 S and 34 S/32 S) between
aqueous SO 4, H 2 S, and coexisting pyrite under hydrothermal conditions were determined …
aqueous SO 4, H 2 S, and coexisting pyrite under hydrothermal conditions were determined …
Experimental and theoretical studies on kinetics for thermochemical sulfate reduction of oil, C2–5 and methane
To address the kinetic parameters for thermochemical sulfate reduction (TSR) of oil and
hydrocarbon gases, hydrothermal experiments involving oil or methane and sulfate at 50 …
hydrocarbon gases, hydrothermal experiments involving oil or methane and sulfate at 50 …
Experimental determination of gold speciation in sulfide-rich hydrothermal fluids under a wide range of redox conditions
AL Trigub, BR Tagirov, KO Kvashnina, S Lafuerza… - Chemical …, 2017 - Elsevier
The redox state of hydrothermal fluids, which form economic deposits of noble metals, varies
in wide limits–from oxidized ones typical for porphyry mineralization to reduced, which form …
in wide limits–from oxidized ones typical for porphyry mineralization to reduced, which form …