Connecting theory and simulation with experiment for the study of diffusion in nanoporous solids

BC Bukowski, FJ Keil, PI Ravikovitch, G Sastre… - Adsorption, 2021 - Springer
Nanoporous solids are ubiquitous in chemical, energy, and environmental processes, where
controlled transport of molecules through the pores plays a crucial role. They are used as …

[HTML][HTML] Xenon gas separation and storage using metal-organic frameworks

D Banerjee, CM Simon, SK Elsaidi, M Haranczyk… - Chem, 2018 - cell.com
The global demand for Xenon (Xe), a noble gas with applications in electronics, lighting, and
the medical industry, is expected to increase significantly over the coming decades …

Crystal engineering, structure–function relationships, and the future of metal–organic frameworks

MD Allendorf, V Stavila - CrystEngComm, 2015 - pubs.rsc.org
Metal–Organic Frameworks (MOFs) are a rapidly expanding class of hybrid organic–
inorganic materials that can be rationally designed and assembled through crystal …

Extension of the universal force field for metal–organic frameworks

DE Coupry, MA Addicoat, T Heine - Journal of Chemical Theory …, 2016 - ACS Publications
We have extended the Universal Force Field for Metal–Organic Frameworks (UFF4MOF) to
cover all moieties present in the most extensive framework library to date, ie, the …

Combined deep learning and classical potential approach for modeling diffusion in UiO-66

SK Achar, JJ Wardzala, L Bernasconi… - Journal of Chemical …, 2022 - ACS Publications
Modeling of diffusion of adsorbates through porous materials with atomistic molecular
dynamics (MD) can be a challenging task if the flexibility of the adsorbent needs to be …

Temperature and loading-dependent diffusion of light hydrocarbons in ZIF-8 as predicted through fully flexible molecular simulations

RJ Verploegh, S Nair, DS Sholl - Journal of the American …, 2015 - ACS Publications
Accurate and efficient predictions of hydrocarbon diffusivities in zeolitic imidazolate
frameworks (ZIFs) are challenging, due to the small pore size of materials such as ZIF-8 and …

Ewald summation for molecular simulations

BA Wells, AL Chaffee - Journal of chemical theory and …, 2015 - ACS Publications
Ewald summation is an important technique for molecular simulation. In this article,
expressions are provided for implementing Ewald summation for any inverse power …

Rotational dynamics of linkers in metal–organic frameworks

A Gonzalez-Nelson, FX Coudert, MA van Der Veen - Nanomaterials, 2019 - mdpi.com
Among the numerous fascinating properties of metal–organic frameworks (MOFs), their
rotational dynamics is perhaps one of the most intriguing, with clear consequences for …

[HTML][HTML] MOF-based MMMs breaking the upper bounds of polymers for a large variety of gas separations

H Daglar, S Aydin, S Keskin - Separation and Purification Technology, 2022 - Elsevier
Mixed matrix membranes (MMMs) are a strong alternative to the conventional polymeric
membranes which suffer from a trade-off between selectivity and gas permeability …

Insights into mass transfer barriers in metal–organic frameworks

BC Bukowski, FA Son, Y Chen, L Robison… - Chemistry of …, 2022 - ACS Publications
Identifying mass transfer limitations is imperative for the practical application of nanoporous
solids in adsorptive separations and catalysis. In particular, metal–organic frameworks …