Theoretical studies of atmospheric reaction mechanisms in the troposphere

L Vereecken, JS Francisco - Chemical Society Reviews, 2012 - pubs.rsc.org
The chemistry of the atmosphere encompasses a vast number of reactions acting on a
plethora of intermediates. These reactions, occurring sequentially and in parallel, give rise to …

Real-time air quality forecasting, part II: State of the science, current research needs, and future prospects

Y Zhang, M Bocquet, V Mallet, C Seigneur… - Atmospheric …, 2012 - Elsevier
The review of major 3-D global and regional real-time air quality forecasting (RT-AQF)
models in Part I identifies several areas of improvement in meteorological forecasts …

[HTML][HTML] Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO measurements

V Shah, DJ Jacob, R Dang, LN Lamsal… - Atmospheric …, 2023 - acp.copernicus.org
Satellite-based retrievals of tropospheric NO 2 columns are widely used to infer NO x (≡
NO+ NO 2) emissions. These retrievals rely on model information for the vertical distribution …

Direct electroconversion of air to nitric acid under mild conditions

S Chen, S Liang, R Huang, M Zhang, Y Song… - Nature …, 2024 - nature.com
Nitric acid (HNO3) synthesis is an important industrial process but typically requires multiple
energy-intensive steps, including the synthesis and subsequent oxidation of ammonia. Here …

Atmospheric NOx oxidation as major sources for nitrous acid (HONO)

M Song, X Zhao, P Liu, J Mu, G He, C Zhang… - npj Climate and …, 2023 - nature.com
Nitrous acid (HONO) is the major precursor of hydroxyl (OH) radicals to initiate tropospheric
chemistry leading to formation of secondary pollutants. The sources of atmospheric HONO …

Atmospheric ammonia and particulate inorganic nitrogen over the United States

CL Heald, JL Collett Jr, T Lee… - Atmospheric …, 2012 - acp.copernicus.org
We use in situ observations from the Interagency Monitoring of PROtected Visual
Environments (IMPROVE) network, the Midwest Ammonia Monitoring Project, 11 surface site …

Missing OH source in a suburban environment near Bei**g: observed and modelled OH and HO2 concentrations in summer 2006

KD Lu, A Hofzumahaus, F Holland… - Atmospheric …, 2013 - acp.copernicus.org
Measurements of ambient OH and HO 2 radicals were performed by laser induced
fluorescence (LIF) during CAREBei**g2006 (Campaigns of Air Quality Research in Bei**g …

Key chemical NOx sink uncertainties and how they influence top-down emissions of nitrogen oxides

T Stavrakou, JF Müller, KF Boersma… - Atmospheric …, 2013 - acp.copernicus.org
Triggered by recent developments from laboratory and field studies regarding major NO x
sink pathways in the troposphere, this study evaluates the influence of chemical …

Mid-infrared time-resolved frequency comb spectroscopy of transient free radicals

AJ Fleisher, BJ Bjork, TQ Bui, KC Cossel… - The journal of …, 2014 - ACS Publications
We demonstrate time-resolved frequency comb spectroscopy (TRFCS), a new broadband
absorption spectroscopy technique for the study of trace free radicals on the microsecond …

Atmospheric chemistry of isoflurane, desflurane, and sevoflurane: kinetics and mechanisms of reactions with chlorine atoms and OH radicals and global warming …

MP Sulbaek Andersen, OJ Nielsen… - The Journal of …, 2012 - ACS Publications
The smog chamber/Fourier-transform infrared spectroscopy (FTIR) technique was used to
measure the rate coefficients k (Cl+ CF3CHClOCHF2, isoflurane)=(4.5±0.8)× 10–15, k (Cl+ …