Recent developments on the potential biological applications of transition metal complexes of thiosemicarbazone derivatives

V Singh, VNV Palakkeezhillam, V Manakkadan… - Polyhedron, 2023 - Elsevier
This review talks about the synthesis, and coordination chemistry of thiosemicarbazone and
its bonding with transition metals like copper, nickel, zinc, palladium, and ruthenium and …

Development of thiosemicarbazone-based transition metal complexes as homogeneous catalysts for various organic transformations

S Priyarega, J Haribabu, R Karvembu - Inorganica Chimica Acta, 2022 - Elsevier
Thiosemicarbazones, an important class of sulphur donor ligands, and their transition metal
complexes are known for their versatile applications in the fields of (bio) catalysis …

Inspired by Nature—Functional Analogues of Molybdenum and Tungsten-Dependent Oxidoreductases

S Pätsch, JV Correia, BJ Elvers, M Steuer, C Schulzke - Molecules, 2022 - mdpi.com
Throughout the previous ten years many scientists took inspiration from natural molybdenum
and tungsten-dependent oxidoreductases to build functional active site analogues. These …

New molybdenum (VI) complexes with thiazole-hydrazone ligand: preparation, structural characterization, and catalytic applications in olefin epoxidation

M Ghorbanloo, R Bikas, G Małecki - Inorganica Chimica Acta, 2016 - Elsevier
The reaction of [MoO 2 (acac) 2] with (E)-2-((2-(benzo [d] thiazol-2-yl) hydrazono) methyl)-6-
methoxyphenol (H 2 L), in acetonitrile and ethanol resulted in the formation of {[MoO 2 …

Thiosemicarbazone complexes of transition metals as catalysts for cross-coupling reactions

ID Kostas, BR Steele - Catalysts, 2020 - mdpi.com
Catalysis of cross-coupling reactions under phosphane-free conditions represents an
important ongoing challenge. Although transition metal complexes based on the …

Ruthenium (II) carbonyl complexes containing pyridoxal thiosemicarbazone and trans-bis (triphenylphosphine/arsine): Synthesis, structure and their recyclable …

R Manikandan, P Anitha, G Prakash, P Vijayan… - Journal of Molecular …, 2015 - Elsevier
Abstract Pyridoxal N (4)-substituted thisemicarbazone hydrochloride ligands (L 1–3) were
synthesized and reacted with the ruthenium (II) starting complexes [RuHCl (CO)(EPh 3) …

Ultrasonic assisted synthesis, crystallographic, spectroscopic studies and biological activity of three new Zn (II), Co (II) and Ni (II) thiosemicarbazone complexes as …

Z Piri, Z Moradi–Shoeili, A Assoud - Inorganica Chimica Acta, 2019 - Elsevier
Using ultrasonic irradiations, three new complexes of type [ZnL 2]. CH 3 CN,[NiLCl] and
[CoL 2](where L is 2-acetylpyridine-4N-p-chlorophenylthiosemicarbazone ligand) have …

Synthesis, spectroscopy, electrochemistry, crystal structures and in vitro cytotoxicity of mononuclear molybdenum (VI) complexes incorporating tridentate ONO donor …

TM Asha, MRP Kurup - Inorganica Chimica Acta, 2018 - Elsevier
Four new mononuclear cis-dioxidomolybdenum (VI) complexes with the general formula
[MoO 2 LD], where H 2 L= tridentate aroylhydrazone and D= MeOH, pyridine (py), imidazole …

Dioxomolybdenum (VI) complexes with 3-methoxy salicylidene-N-alkyl substituted thiosemicarbazones. Synthesis, characterization, enzyme inhibition and antioxidant …

S Eğlence-Bakır, O Sacan, M Şahin, R Yanardag… - Journal of Molecular …, 2019 - Elsevier
methoxysalicylidene N-alkyl-thiosemicarbazones (L)(where alkyl is propyl, butyl, pentyl or
hexyl) were synthesized. The reaction of the ONS donor ligands with [MoO 2 (acac) 2] in …

Fe (ii) complexes of pyridine-substituted thiosemicarbazone ligands as catalysts for oxidations with hydrogen peroxide

CE Castillo, MA Gonzálvez, AG Algarra… - Dalton …, 2023 - pubs.rsc.org
The reaction of three [FeII (TSC) 2] complexes, where TSC is a pyridine-substituted
thiosemicarbazone of the HDpT or HBpT families, with H2O2 in acetonitrile solution does not …