The development of novel synthetic strategies to form new chemical entities in a
stereoselective manner is an ongoing significant objective in organic and medicinal …

3-Substituted-3-aminooxindoles have attracted the attention of organic chemists since they
have a common core structural motif found in many natural products and biologically active …

In this report, we establish that DM-Segphos copper (I) complexes are efficient catalysts for
the enantioselective borylation of para-quinone methides. This method provides …

Phosphine‐catalyzed enantioselective annulation reactions involving ketimines are a
daunting synthetic challenge owing to the intrinsic low reactivity of ketimine substrates. A …

A highly efficient and practical one-pot sequential process, consisting of an organocatalytic
enantioselective Friedel–Crafts-type addition of 4-nonsubstituted pyrazolones to isatin …

Enantioselective electrophilic three-component thioarylation of alkenes by chiral selenide
catalysis with free phenols as arylating sources is disclosed. A variety of chiral phenols were …

Highly enantioselective rhodium‐catalyzed addition of arylboroxines to N‐unprotected
ketimines is realized for the first time by employing chiral BIBOP‐type ligands with a Rh …

Asymmetric synthesis of pharmacologically interesting piperidine-fused spiro-oxindole
derivatives has been achieved via an organocatalytic Michael/aza-Henry/hemiaminalization …

N‐Boc ketimines derived from pyrazolin‐5‐ones were explored to develop an
unprecedented domino aza‐Friedel–Crafts/N, O‐acetalization reaction with 2‐naphthols …

The catalytic asymmetric dearomatization reaction of non-functionalized arenes poses a
long-standing synthetic challenge to organic chemists because of the relative ease of …