Microkinetic modeling: a tool for rational catalyst design

AH Motagamwala, JA Dumesic - Chemical Reviews, 2020 - ACS Publications
The design of heterogeneous catalysts relies on understanding the fundamental surface
kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help …

Heterogeneous catalysis

R Schlögl - Angewandte Chemie International Edition, 2015 - Wiley Online Library
A heterogeneous catalyst is a functional material that continually creates active sites with its
reactants under reaction conditions. These sites change the rates of chemical reactions of …

Progress in the direct catalytic conversion of methane to fuels and chemicals

C Karakaya, RJ Kee - Progress in Energy and Combustion Science, 2016 - Elsevier
This paper reviews the state-of-the-art in catalytic processes to convert methane (a major
component of natural gas) to more valuable hydrocarbons as fuels or chemicals. The scope …

Aerobic oxidations of light alkanes over solid metal oxide catalysts

JT Grant, JM Venegas, WP McDermott… - Chemical …, 2017 - ACS Publications
Heterogeneous metal oxide catalysts are widely studied for the aerobic oxidations of C1–C4
alkanes to form olefins and oxygenates. In this review, we outline the properties of supported …

Direct conversion of methane to fuels and chemicals

A Holmen - Catalysis today, 2009 - Elsevier
Direct selective conversion of methane to C2-hydrocarbons, methanol or aromatics
represents a formidable challenge to catalysis. This has become more and more evident …

High-throughput experimentation and catalyst informatics for oxidative coupling of methane

TN Nguyen, TTP Nhat, K Takimoto, A Thakur… - Acs …, 2019 - ACS Publications
The presence of a dataset that covers a parametric space of materials and process
conditions in a process-consistent manner is essential for the realization of catalyst …

Catalytic routes for direct methane conversion to hydrocarbons and hydrogen: current state and opportunities

H Cruchade, IC Medeiros-Costa, N Nesterenko… - ACS …, 2022 - ACS Publications
Natural gas, the cleanest fossil fuel, is an abundant source of methane and expected to play
an increasingly important role in powering the world's economic growth over the energy …

Revisiting the oxidative coupling of methane to ethylene in the golden period of shale gas: A review

A Galadima, O Muraza - Journal of Industrial and Engineering Chemistry, 2016 - Elsevier
Catalytic upgrading of methane in natural gas and/or shale gas via oxidative methane
coupling (OMC) is an important option tailored by industry for meeting the global ethylene …

Direct methane conversion routes to chemicals and fuels

MC Alvarez-Galvan, N Mota, M Ojeda, S Rojas… - Catalysis today, 2011 - Elsevier
This paper addresses the options developed over the past two decades for the conversion of
methane into valuable chemicals and fuels while avoiding the high energy requirements of …

A viewpoint on direct methane conversion to ethane and ethylene using oxidative coupling on solid catalysts

BL Farrell, VO Igenegbai, S Linic - Acs Catalysis, 2016 - ACS Publications
Over the last several decades, extensive research has focused on the direct conversion of
methane to alcohols or higher hydrocarbons. Research in this field has intensified in recent …