Reduction of substrates by nitrogenases
Nitrogenase is the enzyme that catalyzes biological N2 reduction to NH3. This enzyme
achieves an impressive rate enhancement over the uncatalyzed reaction. Given the high …
achieves an impressive rate enhancement over the uncatalyzed reaction. Given the high …
Mechanism of nitrogen fixation by nitrogenase: the next stage
Nitrogen is an essential element contained in many biomolecules necessary to sustain life.
1, 2 This element is abundantly available in Earth's atmosphere in the form of dinitrogen …
1, 2 This element is abundantly available in Earth's atmosphere in the form of dinitrogen …
An amorphous noble‐metal‐free electrocatalyst that enables nitrogen fixation under ambient conditions
N2 fixation by the electrocatalytic nitrogen reduction reaction (NRR) under ambient
conditions is regarded as a potential approach to achieve NH3 production, which still …
conditions is regarded as a potential approach to achieve NH3 production, which still …
Catalytic conversion of nitrogen to ammonia by an iron model complex
The reduction of nitrogen (N2) to ammonia (NH3) is a requisite transformation for life.
Although it is widely appreciated that the iron-rich cofactors of nitrogenase enzymes facilitate …
Although it is widely appreciated that the iron-rich cofactors of nitrogenase enzymes facilitate …
Metal-free black phosphorus nanosheets-decorated graphitic carbon nitride nanosheets with CP bonds for excellent photocatalytic nitrogen fixation
P Qiu, C Xu, N Zhou, H Chen, F Jiang - Applied catalysis B: environmental, 2018 - Elsevier
Visible light photocatalytic nitrogen fixation, as a low-cost and mild technology, needs efforts
to explore an economical photocatalyst with high activity and stability. In this study, a metal …
to explore an economical photocatalyst with high activity and stability. In this study, a metal …
The spectroscopy of nitrogenases
Nitrogenases are responsible for biological nitrogen fixation, a crucial step in the
biogeochemical nitrogen cycle. These enzymes utilize a two-component protein system and …
biogeochemical nitrogen cycle. These enzymes utilize a two-component protein system and …
Kinetic isotope effects in the study of organometallic reaction mechanisms
Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …
Photochemical nitrogen conversion to ammonia in ambient conditions with FeMoS-chalcogels
In nature, nitrogen fixation is one of the most important life processes and occurs primarily in
microbial organisms containing enzymes called nitrogenases. These complex proteins …
microbial organisms containing enzymes called nitrogenases. These complex proteins …
A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia
The synthesis of transition metal–dinitrogen complexes and the stoichiometric
transformation of their coordinated dinitrogen into ammonia and hydrazine have been the …
transformation of their coordinated dinitrogen into ammonia and hydrazine have been the …
Black phosphorus-based heterostructures for photocatalysis and photoelectrochemical water splitting
Semiconductor-based photocatalytic and photoelectrochemical (PEC) processes can
convert solar energy into high-density chemical energy or for the treatment of environmental …
convert solar energy into high-density chemical energy or for the treatment of environmental …