Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

The present review offers an overview of nonclassical (eg, with no pre-or in situ activation of
a carboxylic acid partner) approaches for the construction of amide bonds. The review aims …

Conspectus Owing to the prevalence of nitrogen-containing compounds in functional
materials, natural products and important pharmaceutical agents, chemists have actively …

The transition-metal-catalyzed addition of C–H bonds to carbonyls, imines, and related
polarized π bonds has emerged as a particularly efficient and powerful approach for the …

Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …

Benzoyl azides were used for the direct and atom economic C–H amidation of electron rich
heteroarenes in the presence of phosphoric acid, a photocatalyst and visible light. Hetero …

This feature article provides an overview of the application of organic azides for the
intermolecular amination of sp3 and sp2 C–H bonds. The catalytic activity of several metal …

Abstract Expedient C H aminocarbonylations of unactivated (hetero) arenes and alkenes
were accomplished with a cobalt (III) catalyst that shows high functional group tolerance …

A visible-light-promoted and simple iron salt-catalyzed N-arylation was achieved efficiently
under external photosensitizer-free conditions. Arylboronic acids and bench-stable …

The practical aspects of Cp* Rh (III)-catalyzed direct C–H amidation with 1, 4, 2-dioxazol-5-
ones were investigated on the operational safety, use of green solvent, and scalability …