Molecular views on Fischer–Tropsch synthesis

KT Rommens, M Saeys - Chemical Reviews, 2023 - ACS Publications
For nearly a century, the Fischer–Tropsch (FT) reaction has been subject of intense debate.
Various molecular views on the active sites and on the reaction mechanism have been …

Status and prospects in higher alcohols synthesis from syngas

HT Luk, C Mondelli, DC Ferré, JA Stewart… - Chemical Society …, 2017 - pubs.rsc.org
Higher alcohols are important compounds with widespread applications in the chemical,
pharmaceutical and energy sectors. Currently, they are mainly produced by sugar …

An overview of Fischer-Tropsch Synthesis: XtL processes, catalysts and reactors

M Martinelli, MK Gnanamani, S LeViness… - Applied Catalysis A …, 2020 - Elsevier
This review is divided into three main sections. The first section of this overview examines in
detail recent techno-economic analyses on the utilization of biomass as a source of syngas …

MOF-Derived Ru1Zr1/Co Dual-Atomic-Site Catalyst with Promoted Performance for Fischer–Tropsch Synthesis

J Sun, L Tao, C Ye, Y Wang, G Meng… - Journal of the …, 2023 - ACS Publications
Cobalt-based catalysts have been widely used for Fischer–Tropsch synthesis (FTS) in
industry; however, achieving rational catalyst design at the atomic level and thereby a higher …

The oscillating fischer-tropsch reaction

R Zhang, Y Wang, P Gaspard, N Kruse - Science, 2023 - science.org
The mechanistic steps that underlie the formation of higher hydrocarbons in catalytic carbon
monoxide (CO) hydrogenation at atmospheric pressure over cobalt-based catalysts (Fischer …

Mechanism and microkinetics of the Fischer–Tropsch reaction

RA Van Santen, AJ Markvoort, IAW Filot… - Physical Chemistry …, 2013 - pubs.rsc.org
The increasing availability of quantum-chemical data on surface reaction intermediates
invites one to revisit unresolved mechanistic issues in heterogeneous catalysis. One such …

CO chemisorption and dissociation at high coverages during CO hydrogenation on Ru catalysts

BT Loveless, C Buda, M Neurock… - Journal of the American …, 2013 - ACS Publications
Density functional theory (DFT) and infrared spectroscopy results are combined with
mechanism-based rate equations to assess the structure and thermodynamics of …

Fischer-Tropsch synthesis: catalysts and chemistry

J Van de Loosdrecht, FG Botes, IM Ciobica… - … Inorganic Chemistry II …, 2013 - research.tue.nl
Abstract The Fischer–Tropsch synthesis represents a time-tested and fully proven
technology for the conversion of synthesis gas (CO+ H2) into paraffins, olefins, and …

Size-dependent dissociation of carbon monoxide on cobalt nanoparticles

A Tuxen, S Carenco, M Chintapalli… - Journal of the …, 2013 - ACS Publications
In situ soft X-ray absorption spectroscopy (XAS) was employed to study the adsorption and
dissociation of carbon monoxide molecules on cobalt nanoparticles with sizes ranging from …

An overview of low-temperature fischer–tropsch synthesis: Market conditions, raw materials, reactors, scale-up, process intensification, mechanisms, and outlook

JE Apolinar-Hernández, SL Bertoli, HG Riella… - Energy & …, 2023 - ACS Publications
The Fischer–Tropsch technology has allowed, since its emergence a century ago, the
production of stable liquid fuels from different raw materials in different geographic scenarios …