An overview of anticancer platinum N-heterocyclic carbene complexes

S Zhao, Z Yang, G Jiang, S Huang, M Bian, Y Lu… - Coordination Chemistry …, 2021 - Elsevier
N-Heterocyclic carbenes (NHCs) have been introduced as a new platform for the
development of anticancer metal complexes for several decades. NHCs as strong σ-donors …

Platinum iodido complexes: A comprehensive overview of anticancer activity and mechanisms of action

P Štarha, J Vančo, Z Trávníček - Coordination Chemistry Reviews, 2019 - Elsevier
Platinum iodido complexes have long been recognized as synthetic intermediates of various
platinum complexes (eg, chlorido or carboxylato), including the world-wide used platinum …

Hexaiododiplatinate (ii) as a useful supramolecular synthon for halogen bond involving crystal engineering

AA Eliseeva, DM Ivanov, AS Novikov, AV Rozhkov… - Dalton …, 2020 - pubs.rsc.org
Hexaiododiplatinates (II) bearing ammonium and phosphonium cations,[R4N] 2 [Pt2 (μ-I)
2I4]{R= Et (1) and n-Bu (2)} and [R3PR1] 2 [Pt2 (μ-I) 2I4]{R= n-Bu and R1= n-Bu (3); R= Ph …

Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis

VM Chernyshev, OV Khazipov, MA Shevchenko… - Chemical …, 2018 - pubs.rsc.org
Numerous reactions are catalyzed by complexes of metals (M) with N-heterocyclic carbene
(NHC) ligands, typically in the presence of oxygen bases, which significantly shape the …

Fast and slow release of catalytically active species in metal/NHC systems induced by aliphatic amines

OV Khazipov, MA Shevchenko, AY Chernenko… - …, 2018 - ACS Publications
The behavior of ubiquitously used nickel, palladium, and platinum complexes containing N-
heterocyclic carbene ligands was studied in solution in the presence of aliphatic amines …

Developments in the chemistry of stibine and bismuthine complexes

VK Greenacre, W Levason, G Reid - Coordination Chemistry Reviews, 2021 - Elsevier
New findings in the coordination chemistry of neutral stibine and bismuthine ligands are
reviewed. The article describes new ligand syntheses, coordination complexes of d-block …

Exploring diversity in platinum (IV) N-heterocyclic carbene complexes: Synthesis, characterization, reactivity and biological evaluation

M Bouché, A Bonnefont, T Achard… - Dalton …, 2018 - pubs.rsc.org
Platinum (IV) complexes stabilized by N-heterocyclic carbene ligands of the type [(NHC)
PtX4L], where L is a neutral nitrogen-based ligand and X is a halide anion (Br, Cl), were …

Mixed Arylolefin/NHC Complexes of Platinum(II): Syntheses, Characterizations, and In Vitro Cytotoxicities

NTT Chi, VT Pham, HV Huynh - Organometallics, 2020 - ACS Publications
Eight platinum (II) complexes of the formula [PtCl (arylolefin)(NHC)](2–9) with varying NHCs
and arylolefin chelators have been prepared and analyzed by spectroscopic and …

N, N-Dialkylbenzimidazol-2-ylidene platinum complexes–effects of alkyl residues and ancillary cis-ligands on anticancer activity

T Rehm, M Rothemund, A Bär, T Dietel, R Kempe… - Dalton …, 2018 - pubs.rsc.org
Eleven complexes of [(1, 3-dialkylbenzimidazol-2-ylidene) LnCl3− n] Pt (n− 1)+, with Ln=
DMSO (8), Ph3P (9),(Ph3P) 2 (10), and alkyl= Me (a), Et (b), Bu (c), octyl (d), were …

Iodide analogs of arsenoplatins—potential drug candidates for triple negative breast cancers

Ð Miodragović, W Qiang, Z Sattar Waxali, Ž Vitnik… - Molecules, 2021 - mdpi.com
Patients with triple negative breast cancers (TNBCs)—highly aggressive tumors that do not
express estrogen, progesterone, and human epidermal growth factor 2 receptors—have …