Differentiating between two highly similar C–H bonds in a given molecule remains a
fundamental challenge in synthetic organic chemistry. Directing group assisted strategies for …

In the arena of functional group‐oriented organic synthesis, nitrile or cyano functionality is of
immense importance. The presence of nucleophilic N‐atom, π‐coordinating ability of the …

Anilines are important moieties in organic chemistry, pharmaceuticals, and materials
science. Although para-selective functionalization of anilides and tertiary anilines is well …

The recently developed palladium-catalyzed C (sp2)–H olefination of 2-arylbenzaldehyde
with the aid of a temporary directing group (TDG) via reversible imine formation delivers …

Controlling regioselectivity in C− H functionalizations is a key challenge in chemical method
development. In arenes, functionalizations are most difficult to direct towards the C− H group …

Site‐specific modification of thiol‐containing biomolecules has been recognized as a
versatile and powerful strategy for probing our biological systems and discovering novel …

Herein we report a transition metal-free approach for the regioselective functionalization of
benzylic C (sp 3) single bondH bonds in the presence of various heterocyclic amines as …

A mild strategy for oxidative Csp2-H arylation of electron-rich furans and pyrroles has been
achieved with the aid of remote carbonyl-containing groups. These groups enable the Pd …

Achieving high para-selective C–H functionalized products of benzoic acid derivatives using
a designed template is still a daunting challenge because the carbonyl group also could …

A Pd (II)‐catalyzed non‐template synthesis of furo [2, 3‐b] pyrrolo [2, 3‐d] pyridines from β‐
ketodinitriles and buta‐1, 3‐diynes has been accomplished via dual annulative cyclization …