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Cyanide‐bridged molecular squares offer a unique opportunity for study, as they represent a
model of the simplest unit of Prussian blue and allow access to a wide range of physical …

Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

A series of isostructural cyano‐bridged MnIII (hs)–MIII (ls) alternating chains,[MnIII (5‐
TMAMsalen) MIII (CN) 6]⋅ 4H2O (5‐TMAMsalen2−= N, N′‐ethylenebis (5 …

Octacyanidometallates make an important branch of cyanide-based molecular magnets that
not only follow the trends in modern magnetochemistry and materials science but also have …

The cyanido-bridged square-like molecules with d/f metal ions occupying the corners of the
square are considered molecular models of the Prussian Blue Analogues (PBAs) because …

Three seven-coordinate lanthanide (III) sandwich-type mononuclear complexes with π-
conjugated TTF-Schiff base ligand H2L (L2–= 2, 2′-((2-(4, 5-bis (methylthio)-1, 3-dithiol-2 …

Nucleophilic aromatic substitution (SNAr) is a class of reaction that has become very
important over time. This type of transformation usually proceeds without the use of metal …

A new symmetrical tricyanide building block mer-[Fe (bbp)(CN) 3] 2–[1; bbp= bis (2-
benzimidazolyl) pyridine dianion] has been prepared and structurally and magnetically …

On the basis of high-spin metal–cyanide clusters of MnIII6MIII (M= Cr, Fe, Co), three one-
dimensional (1D) chain complexes,[Mn (salen)] 6 [Cr (CN) 6] 2· 6CH3OH· H2O (1),[Mn (5 …