Recent progress with pincer transition metal catalysts for sustainability
L Piccirilli, D Lobo Justo Pinheiro, M Nielsen - Catalysts, 2020 - mdpi.com
Our planet urgently needs sustainable solutions to alleviate the anthropogenic global
warming and climate change. Homogeneous catalysis has the potential to play a …
warming and climate change. Homogeneous catalysis has the potential to play a …
An update on formic acid dehydrogenation by homogeneous catalysis
Formic acid (FA) has been extensively studied as one of the most promising hydrogen
energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of …
energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of …
Versatile CO2 Hydrogenation–Dehydrogenation Catalysis with a Ru–PNP/Ionic Liquid System
L Piccirilli, B Rabell, R Padilla, A Riisager… - Journal of the …, 2023 - ACS Publications
High catalytic activities of Ru–PNP [Ru= ruthenium; PNP= bis alkyl-or aryl
ethylphosphinoamine complexes in ionic liquids (ILs) were obtained for the reversible …
ethylphosphinoamine complexes in ionic liquids (ILs) were obtained for the reversible …
Formic acid as a potential on‐board hydrogen storage method: Development of homogeneous noble metal catalysts for dehydrogenation reactions
J Guo, CK Yin, DL Zhong, YL Wang, T Qi… - …, 2021 - Wiley Online Library
Hydrogen can be used as an energy carrier for renewable energy to overcome the
deficiency of its intrinsically intermittent supply. One of the most promising application of …
deficiency of its intrinsically intermittent supply. One of the most promising application of …
Tri-metallic AuPdIr nanoalloy towards efficient hydrogen generation from formic acid
Formic acid (FA), as a safe and renewable hydrogen storage material, attracts extensive
attention. Herein, an efficient catalyst Au 0.35 Pd 0.5 Ir 0.15 nanoalloy supported on NH 2-N …
attention. Herein, an efficient catalyst Au 0.35 Pd 0.5 Ir 0.15 nanoalloy supported on NH 2-N …
Catalytic oxidations by dehydrogenation of alkanes, alcohols and amines with defined (non)-noble metal pincer complexes
S Budweg, K Junge, M Beller - Catalysis Science & Technology, 2020 - pubs.rsc.org
The present review highlights the latest developments in the field of transition metal-
catalysed oxidations, in particular C–C–, C–O–and C–N-bond dehydrogenations. Defined …
catalysed oxidations, in particular C–C–, C–O–and C–N-bond dehydrogenations. Defined …
Formic acid dehydrogenation using Ruthenium-POP pincer complexes in ionic liquids
AT Nikol, B Rabell, MSB Jørgensen, RW Larsen… - Scientific Reports, 2024 - nature.com
Formic acid is one of the most promising candidates for the long-term storage of hydrogen in
liquid form. Herein, we present a new collection of ruthenium pincer complexes of the …
liquid form. Herein, we present a new collection of ruthenium pincer complexes of the …
Efficient additive-free formic acid dehydrogenation with a NNN–ruthenium complex
A new ruthenium complex containing a pyridylidene amine-based NNN ligand was
developed as a catalyst precursor for formic acid dehydrogenation, which, as a rare …
developed as a catalyst precursor for formic acid dehydrogenation, which, as a rare …
Control of Catalyst Isomers Using an N-Phenyl-Substituted RN(CH2CH2PiPr2)2 Pincer Ligand in CO2 Hydrogenation and Formic Acid Dehydrogenation
JB Curley, C Hert, WH Bernskoetter, N Hazari… - Inorganic …, 2021 - ACS Publications
A novel pincer ligand, iPrPNPhP [PhN (CH2CH2PiPr2) 2], which is an analogue of the
versatile MACHO ligand, iPrPNHP [HN (CH2CH2PiPr2) 2], was synthesized and …
versatile MACHO ligand, iPrPNHP [HN (CH2CH2PiPr2) 2], was synthesized and …
Efficient and selective catalytic hydrogenation of furanic aldehydes using well defined Ru and Ir pincer complexes
We report the homogeneous catalytic hydrogenation of biomass derived furanic aldehydes
to furfuryl alcohols using low loadings of PNP metal complexes under mild conditions. Our …
to furfuryl alcohols using low loadings of PNP metal complexes under mild conditions. Our …