[HTML][HTML] Recent developments in the use of peroxygenases–Exploring their high potential in selective oxyfunctionalisations
Peroxygenases are an emerging new class of enzymes allowing selective
oxyfunctionalisation reactions in a cofactor-independent way different from well-known P450 …
oxyfunctionalisation reactions in a cofactor-independent way different from well-known P450 …
Hydrogen peroxide driven biocatalysis
In general, hydrogen peroxide is a stable and relatively mild oxidant and it can be regarded
as the ultimate “green” reagent because water and oxygen are the only by-products …
as the ultimate “green” reagent because water and oxygen are the only by-products …
[HTML][HTML] Peroxygenases en route to becoming dream catalysts. What are the opportunities and challenges?
Highlights•Peroxygenases are very promising catalysts for preparative oxyfunctionalization
chemistry.•The number of interesting applications and novel catalysts is growing …
chemistry.•The number of interesting applications and novel catalysts is growing …
Oxidations catalyzed by fungal peroxygenases
M Hofrichter, R Ullrich - Current opinion in chemical biology, 2014 - Elsevier
Highlights•Selective oxyfunctionalizations are among the most challenging reactions in
organic synthesis.•Unspecific peroxygenases (UPO) are a diverse group of secreted fungal …
organic synthesis.•Unspecific peroxygenases (UPO) are a diverse group of secreted fungal …
Structural and Biochemical Studies Enlighten the Unspecific Peroxygenase from Hypoxylon sp. EC38 as an Efficient Oxidative Biocatalyst
L Rotilio, A Swoboda, K Ebner, C Rinnofner… - ACS …, 2021 - ACS Publications
Unspecific peroxygenases (UPOs) are glycosylated fungal enzymes that can selectively
oxidize C–H bonds. UPOs employ hydrogen peroxide as the oxygen donor and reductant …
oxidize C–H bonds. UPOs employ hydrogen peroxide as the oxygen donor and reductant …
Directed evolution of unspecific peroxygenase from Agrocybe aegerita
Unspecific peroxygenase (UPO) represents a new type of heme-thiolate enzyme with self-
sufficient mono (per) oxygenase activity and many potential applications in organic …
sufficient mono (per) oxygenase activity and many potential applications in organic …
Engineering a highly regioselective fungal peroxygenase for the synthesis of hydroxy fatty acids
P Gomez de Santos, A González‐Benjumea… - Angewandte …, 2023 - Wiley Online Library
The hydroxylation of fatty acids is an appealing reaction in synthetic chemistry, although the
lack of selective catalysts hampers its industrial implementation. In this study, we have …
lack of selective catalysts hampers its industrial implementation. In this study, we have …
Evolution of novel wood decay mechanisms in Agaricales revealed by the genome sequences of Fistulina hepatica and Cylindrobasidium torrendii
Wood decay mechanisms in Agaricomycotina have been traditionally separated in two
categories termed white and brown rot. Recently the accuracy of such a dichotomy has been …
categories termed white and brown rot. Recently the accuracy of such a dichotomy has been …
5‐hydroxymethylfurfural conversion by fungal aryl‐alcohol oxidase and unspecific peroxygenase
Oxidative conversion of 5‐hydroxymethylfurfural (HMF) is of biotechnological interest for the
production of renewable (lignocellulose‐based) platform chemicals, such as 2, 5 …
production of renewable (lignocellulose‐based) platform chemicals, such as 2, 5 …
[書籍][B] Monooxygenase, peroxidase and peroxygenase properties and reaction mechanisms of cytochrome P450 enzymes
EG Hrycay, SM Bandiera - 2015 - Springer
This review examines the monooxygenase, peroxidase and peroxygenase properties and
reaction mechanisms of cytochrome P450 (CYP) enzymes in bacterial, archaeal and …
reaction mechanisms of cytochrome P450 (CYP) enzymes in bacterial, archaeal and …