Role of the support in gold-containing nanoparticles as heterogeneous catalysts

M Sankar, Q He, RV Engel, MA Sainna… - Chemical …, 2020 - ACS Publications
In this review, we discuss selected examples from recent literature on the role of the support
on directing the nanostructures of Au-based monometallic and bimetallic nanoparticles. The …

A review on the use of DFT for the prediction of the properties of nanomaterials

P Makkar, NN Ghosh - RSC advances, 2021 - pubs.rsc.org
Nanostructured materials have gained immense attraction because of their extraordinary
properties compared to the bulk materials to be used in a plethora of applications in myriad …

Integrating interactive noble metal single-atom catalysts into transition metal oxide lattices

J Shan, C Ye, C Zhu, J Dong, W Xu… - Journal of the …, 2022 - ACS Publications
Noble metals have broad prospects for catalytic applications yet are restricted to a few
packing modes with limited structural flexibility. Here, we achieved geometric structure …

Towards dense single-atom catalysts for future automotive applications

A Beniya, S Higashi - Nature Catalysis, 2019 - nature.com
CO oxidation is an important primary reaction in automotive catalysis, and has been studied
extensively since the 1970s because of its fundamental nature and technological relevance …

O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

A stable single‐site palladium catalyst for hydrogenations

G Vilé, D Albani, M Nachtegaal, Z Chen… - Angewandte Chemie …, 2015 - Wiley Online Library
We report the preparation and hydrogenation performance of a single‐site palladium
catalyst that was obtained by the anchoring of Pd atoms into the cavities of mesoporous …

Stabilization of single metal atoms on graphitic carbon nitride

Z Chen, S Mitchell, E Vorobyeva… - Advanced Functional …, 2017 - Wiley Online Library
Graphitic carbon nitride (g‐C3N4) exhibits unique properties as a support for single‐atom
heterogeneous catalysts (SAHCs). Understanding how the synthesis method, carrier …

Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries

Y Lu, W Chen - Chemical Society Reviews, 2012 - pubs.rsc.org
Sub-nanometre sized metal clusters, with dimensions between metal atoms and
nanoparticles, have attracted more and more attention due to their unique electronic …

Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …

Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst

IX Green, W Tang, M Neurock, JT Yates Jr - Science, 2011 - science.org
The prevailing view of CO oxidation on gold-titanium oxide (Au/TiO2) catalysts is that the
reaction occurs on metal sites at the Au/TiO2 interface. We observed dual catalytic sites at …