Zeolites in adsorption processes: State of the art and future prospects

E Pérez-Botella, S Valencia, F Rey - Chemical Reviews, 2022 - ACS Publications
Zeolites have been widely used as catalysts, ion exchangers, and adsorbents since their
industrial breakthrough in the 1950s and continue to be state-of the-art adsorbents in many …

Hydrogen isotope separation in confined nanospaces: carbons, zeolites, metal–organic frameworks, and covalent organic frameworks

JY Kim, H Oh, HR Moon - Advanced Materials, 2019 - Wiley Online Library
One of the greatest challenges of modern separation technology is separating isotope
mixtures in high purity. The separation of hydrogen isotopes can create immense economic …

Barely porous organic cages for hydrogen isotope separation

M Liu, L Zhang, MA Little, V Kapil, M Ceriotti, S Yang… - Science, 2019 - science.org
The separation of hydrogen isotopes for applications such as nuclear fusion is a major
challenge. Current technologies are energy intensive and inefficient. Nanoporous materials …

Interfacial thermal resistance between carbon nanotubes: Molecular dynamics simulations and analytical thermal modeling

H Zhong, JR Lukes - Physical Review B—Condensed Matter and Materials …, 2006 - APS
Interfacial thermal transport between offset parallel (10, 10) single-wall carbon nanotubes is
investigated by molecular dynamics simulation and analytical thermal modeling as a …

Quantum sieving for separation of hydrogen isotopes using MOFs

H Oh, M Hirscher - European Journal of Inorganic Chemistry, 2016 - Wiley Online Library
Hydrogen isotope mixtures can be separated either by confinement in small pores
[ie,“kinetic quantum sieving”(KQS)] or by strong adsorption sites [ie,“chemical affinity …

Modelling carbon membranes for gas and isotope separation

Y Jiao, A Du, M Hankel, SC Smith - Physical Chemistry Chemical …, 2013 - pubs.rsc.org
Molecular modelling has become a useful and widely applied tool to investigate separation
and diffusion behavior of gas molecules through nano-porous low dimensional carbon …

Quantum sieving: feasibility and challenges for the separation of hydrogen isotopes in nanoporous materials

J Cai, Y **ng, X Zhao - RSC advances, 2012 - pubs.rsc.org
Quantum effects on the molecular adsorption and migration in confined porous materials
can not be ignored if the difference between the pore size and molecular hard core is no …

Asymmetrically decorated, doped porous graphene as an effective membrane for hydrogen isotope separation

M Hankel, Y Jiao, A Du, SK Gray… - The Journal of Physical …, 2012 - ACS Publications
We propose a new route to hydrogen isotope separation which exploits the quantum sieving
effect in the context of transmission through asymmetrically decorated, doped porous …

Metal-Specific Interactions of H2 Adsorbed within Isostructural Metal–Organic Frameworks

SA FitzGerald, B Burkholder, M Friedman… - Journal of the …, 2011 - ACS Publications
Diffuse reflectance infrared (IR) spectroscopy performed over a wide temperature range (35–
298 K) is used to study the dynamics of H2 adsorbed within the isostructural metal–organic …

Quantum Sieving Effect of Three-Dimensional Cu-Based Organic Framework for H2 and D2

D Noguchi, H Tanaka, A Kondo, H Kajiro… - Journal of the …, 2008 - ACS Publications
The crystal structure of [Cu (4, 4′-bipyridine) 2 (CF3SO3) 2] n metal-organic framework
(CuBOTf) of one-dimensional pore networks after pre-evacuation at 383 K was determined …