Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Evolution of Copolymers of Epoxides and CO2: Catalysts, Monomers, Architectures, and Applications

GW Yang, R **e, YY Zhang, CK Xu, GP Wu - Chemical Reviews, 2024 - ACS Publications
The copolymerization of CO2 and epoxides presents a transformative approach to
converting greenhouse gases into aliphatic polycarbonates (CO2-PCs), thereby reducing …

Quantifying CO2 Insertion Equilibria for Low-Pressure Propene Oxide and Carbon Dioxide Ring Opening Copolymerization Catalysts

KHS Eisenhardt, F Fiorentini… - Journal of the …, 2024 - ACS Publications
While outstanding catalysts are known for the ring-opening copolymerization (ROCOP) of
CO2 and propene oxide (PO), few are reported at low CO2 pressure. Here, a new series of …

Transformation of carbon dioxide with homogeneous transition‐metal catalysts: a molecular solution to a global challenge?

M Cokoja, C Bruckmeier, B Rieger… - Angewandte Chemie …, 2011 - Wiley Online Library
A plethora of methods have been developed over the years so that carbon dioxide can be
used as a reactant in organic synthesis. Given the abundance of this compound, its …

Cobalt catalysts for the coupling of CO 2 and epoxides to provide polycarbonates and cyclic carbonates

XB Lu, DJ Darensbourg - Chemical Society Reviews, 2012 - pubs.rsc.org
This comprehensive tutorial review focuses on well-defined cobalt complexes that serve as
homogeneous catalysts for the production of polycarbonates and cyclic carbonates from the …

Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO2 and Epoxides with Unprecedented Efficiency

GW Yang, YY Zhang, R **e, GP Wu - Journal of the American …, 2020 - ACS Publications
The metallic catalyst-dominated alternating copolymerization of CO2 and epoxides has
flourished for 50 years; however, the involved multistep preparation of the catalysts and the …

The teraton challenge. A review of fixation and transformation of carbon dioxide

M Mikkelsen, M Jørgensen, FC Krebs - Energy & Environmental …, 2010 - pubs.rsc.org
The increase in atmospheric carbon dioxide is linked to climate changes; hence there is an
urgent need to reduce the accumulation of CO2 in the atmosphere. The utilization of CO2 as …

Synthesis of cyclic carbonates from epoxides and CO 2

M North, R Pasquale, C Young - Green Chemistry, 2010 - pubs.rsc.org
Synthesis of cyclic carbonates from epoxides and CO 2 - Green Chemistry (RSC Publishing)
DOI:10.1039/C0GC00065E Royal Society of Chemistry View PDF VersionPrevious ArticleNext …

Transformation of carbon dioxide

T Sakakura, JC Choi, H Yasuda - Chemical reviews, 2007 - ACS Publications
Utilizing renewable resources is a prerequisite for a sustainable society. One easily
available renewable carbon resource is carbon dioxide (CO2), which has the advantages of …

Synergic heterodinuclear catalysts for the ring-opening copolymerization (ROCOP) of epoxides, carbon dioxide, and anhydrides

WT Diment, W Lindeboom, F Fiorentini… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The development of sustainable plastic materials is an essential target of
chemistry in the 21st century. Key objectives toward this goal include utilizing sustainable …