Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …
Mechanochemistry in organic synthesis: An Italian journey through innovations
F Basoccu, L De Luca… - European Journal of …, 2024 - Wiley Online Library
Mechanochemistry, as an enabling technology, harnesses mechanical force to drive
chemical reactions, presenting compelling advantages in organic synthesis within the …
chemical reactions, presenting compelling advantages in organic synthesis within the …
Methods for monitoring milling reactions and mechanistic studies of mechanochemistry: a primer
Mechanochemistry by ball milling is garnering significant attention as an efficient and
versatile means of chemical synthesis which minimizes the need for solvents and reduces …
versatile means of chemical synthesis which minimizes the need for solvents and reduces …
Topological and physical links in soft matter systems
Linking, or multicomponent topological entanglement, is ubiquitous in soft matter systems,
from mixtures of polymers and DNA filaments packed in vivo to interlocked line defects in …
from mixtures of polymers and DNA filaments packed in vivo to interlocked line defects in …
[HTML][HTML] In situ synchrotron X-ray diffraction studies monitoring mechanochemical reactions of hard materials: Challenges and limitations
T Rathmann, H Petersen, S Reichle… - Review of Scientific …, 2021 - pubs.aip.org
In situ monitoring of mechanochemical reactions of soft matter is feasible by synchrotron
diffraction experiments. However, so far, reactions of hard materials in existing polymer …
diffraction experiments. However, so far, reactions of hard materials in existing polymer …
Fast, solvent-free synthesis of ferrocene-containing organic cages via dynamic covalent chemistry in the solid state
A simple, solvent-free synthetic protocol towards the synthesis of organic self-assembled
macromolecules has been established. By employing mechanochemistry using glassware …
macromolecules has been established. By employing mechanochemistry using glassware …
Operando acoustic analysis: a valuable method for investigating reaction mechanisms in mechanochemistry
C Leroy, S Mittelette, G Félix, N Fabregue… - Chemical …, 2022 - pubs.rsc.org
We present a new operando approach for following reactions taking place in
mechanochemistry, relying on the analysis of the evolution of the sound during milling. We …
mechanochemistry, relying on the analysis of the evolution of the sound during milling. We …
Computational evaluation of halogen-bonded cocrystals enables prediction of their mechanochemical interconversion reactions
Periodic density-functional theory (DFT) calculations were used to predict the
thermodynamic stability and the likelihood of interconversion between a series of halogen …
thermodynamic stability and the likelihood of interconversion between a series of halogen …
The mechanochemical beckmann rearrangement over solid acids: From the ball mill to the extruder
Beckmann rearrangement was carried out in the solid state in a ball mill using metal oxides
as solid acids. After a comprehensive investigation of different reaction parameters, acids as …
as solid acids. After a comprehensive investigation of different reaction parameters, acids as …
Listening to the Formation of Polymorphs in a Ball Mill
ÉMS Parlier, K Al Amir, TX Métro, P Granjon… - Analytical …, 2025 - ACS Publications
In this contribution, we apply our newly developed ball-milling operando platform, which
combines Raman spectroscopy and thermal (IR) imaging, as well as acoustic and high …
combines Raman spectroscopy and thermal (IR) imaging, as well as acoustic and high …