Functionalized cyclic organic carbonates and related heterocycles have emerged as highly
versatile heterocyclic substrates for ring‐opening and decarboxylative catalytic …

Palladium‐catalyzed decarboxylative cycloadditions have emerged as highly effective
methods for constructing structurally diverse carbo‐and heterocycles because of the …

Abstract The first catalytic formal [5+ 4] cycloaddition to prepare nine‐membered
heterocycles is presented. Under palladium catalysis, the reaction of N‐tosyl azadienes and …

Inspired by a fungicide, we designed 5-vinyloxazolidine-2, 4-diones as new precursors of π-
allylpalladium zwitterionic intermediates and developed palladium-catalyzed asymmetric …

Abstract A palladium‐catalyzed asymmetric [4+ 2] cycloaddition of 2‐
methylidenetrimethylene carbonate with alkenes derived from pyrazolones, indandione, or …

Medium-sized heterocycles exist in a broad spectrum of biologically active natural products
and medicinally important synthetic compounds. The construction of medium-sized rings …

The nine-membered ring-bearing bicyclo [5.2. 2] tetrahydrooxonines frameworks have
enantioselectively been constructed via a tandem [3+ 2] cycloaddition/Cope rearrangement …

An efficient method for the enantio-and diastereoselective construction of multisubstituted
tetrahydrofurans via asymmetric decarboxylative cycloaddition of vinylethylene carbonates …

The divergent construction of chiral medium-sized rings is an essential but challenging task
in organic synthesis. Herein, we report a temperature-controlled catalytic system for the …

An efficient method for the enantioselective construction of tertiary C–O bond via asymmetric
allylic substitution of racemic vinylethylene carbonates with water and alcohols has been …