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Recent advances in dearomative partial reduction of benzenoid arenes
Dearomative partial reduction is an extraordinary approach for transforming benzenoid
arenes and has been well‐known for many decades, as exemplified by the dehydrogenation …
arenes and has been well‐known for many decades, as exemplified by the dehydrogenation …
Meeting the UN sustainable development goals with mechanochemistry
Chemistry traditionally relies on reactions in solution, but this method is increasingly
problematic due to the scale of chemical processes and their economic and environmental …
problematic due to the scale of chemical processes and their economic and environmental …
Mechanochemical Approach for Air‐Tolerant and Extremely Fast Lithium‐Based Birch Reductions in Minutes
Birch reduction has been widely used in organic synthesis for over half a century as a
powerful method to dearomatize arenes into 1, 4‐cyclohexadiene derivatives. However, the …
powerful method to dearomatize arenes into 1, 4‐cyclohexadiene derivatives. However, the …
Mechanochemical Birch reduction with low reactive alkaline earth metals
Birch reduction and similar dissolved metal‐type transformations hold significant importance
in the organic synthesis toolbox. Historically, the field has been dominated by alkali metal …
in the organic synthesis toolbox. Historically, the field has been dominated by alkali metal …
Alkali metal reduction of alkali metal cations
Counter to synthetic convention and expectation provided by the relevant standard reduction
potentials, the chloroberyllate,[{SiNDipp} BeClLi] 2 [{SiNDipp}={CH2SiMe2N (Dipp)} 2; …
potentials, the chloroberyllate,[{SiNDipp} BeClLi] 2 [{SiNDipp}={CH2SiMe2N (Dipp)} 2; …
s-Block metal complexes of superbulky (t Bu 3 Si) 2 N−: a new weakly coordinating anion?
Sterically hindered amide anions have found widespread application as deprotonation
agents or as ligands to stabilize metals in unusual coordination geometries or oxidation …
agents or as ligands to stabilize metals in unusual coordination geometries or oxidation …
Reduction of K+ or Li+ in the Heterobimetallic Electride K+[LiN(SiMe3)2]e–
Given their very negative redox potential (eg, Li+→ Li (0),− 3.04 V; K+→ K (0),− 2.93 V),
chemical reduction of Group-1 metal cations is one of the biggest challenges in inorganic …
chemical reduction of Group-1 metal cations is one of the biggest challenges in inorganic …
The quest for organo-alkali metal monomers: unscrambling the structure–reactivity relationship
Organo-alkali metal reagents are essential tools in synthetic chemistry. Alkali metal
organometallics aggregate in solution and solid-state forming clusters and polymers. The …
organometallics aggregate in solution and solid-state forming clusters and polymers. The …
Mechanochemical Synthesis, Characterization and Reactivity of a Room Temperature Stable Calcium Electride
A new calcium-based Room temperature Stable Electride (RoSE), K [{Ca [N (Mes)(SiMe3)] 3
(e–)} 2K3](2), is successfully synthesized from the reaction of a calcium tris-amide,[Ca {N …
(e–)} 2K3](2), is successfully synthesized from the reaction of a calcium tris-amide,[Ca {N …
Multi-dimensional inorganic electrides for energy conversion and storage
Reflecting on the course of global development, the progress of high-performance new
materials has played a pivotal role in human history. Researchers are vigorously develo** …
materials has played a pivotal role in human history. Researchers are vigorously develo** …