Insights into single-electron-transfer processes in frustrated Lewis pair chemistry and related donor–acceptor systems in main group chemistry
The activation and utilization of substrates mediated by Frustrated Lewis Pairs (FLPs) was
initially believed to occur solely via a two-electron, cooperative mechanism. More recently …
initially believed to occur solely via a two-electron, cooperative mechanism. More recently …
Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems
M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
Regioselective aliphatic C–H functionalization using frustrated radical pairs
Abstract Frustrated Lewis pairs (FLPs) are well documented for the activation of small
molecules such as dihydrogen and carbon dioxide,,–. Although canonical FLP chemistry is …
molecules such as dihydrogen and carbon dioxide,,–. Although canonical FLP chemistry is …
Frustrated radical pairs in organic synthesis
Frustrated radical pairs (FRPs) describe the phenomenon that two distinct radicals─ which
would otherwise annihilate each other to form a closed-shell covalent adduct─ can coexist …
would otherwise annihilate each other to form a closed-shell covalent adduct─ can coexist …
Heterocyclic nanographenes and other polycyclic heteroaromatic compounds: synthetic routes, properties, and applications
Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic
nanographenes) are a highly versatile class of organic materials, applicable as functional …
nanographenes) are a highly versatile class of organic materials, applicable as functional …
Li‐and Mn‐rich cathode materials: challenges to commercialization
The lithium‐and manganese‐rich (LMR) layered structure cathodes exhibit one of the
highest specific energies (≈ 900 W h kg− 1) among all the cathode materials. However, the …
highest specific energies (≈ 900 W h kg− 1) among all the cathode materials. However, the …
Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals
Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
Methoxy-functionalized triarylamine-based hole-transporting polymers for highly efficient and stable perovskite solar cells
The hole-transporting layer is an essential component in a perovskite solar cell (PSC) and
plays a key role in controlling both power conversion efficiency (PCE) and stability. Here, we …
plays a key role in controlling both power conversion efficiency (PCE) and stability. Here, we …
A radical mechanism for frustrated Lewis pair reactivity
Summary The frustrated Lewis pairs (FLPs) derived from tBu 3 P and E (C 6 F 5) 3 (E= B, Al)
react with pO 2 C 6 Cl 4 and Ph 3 SnH to give [tBu 3 POC 6 Cl 4 OE (C 6 F 5) 3](E= B 1, Al …
react with pO 2 C 6 Cl 4 and Ph 3 SnH to give [tBu 3 POC 6 Cl 4 OE (C 6 F 5) 3](E= B 1, Al …
Radicals derived from Lewis acid/base pairs
While conventional approaches to stabilizing main group radicals have involved the use of
Lewis acids or bases, this tutorial review focuses on new avenues to main group radicals …
Lewis acids or bases, this tutorial review focuses on new avenues to main group radicals …