Flash vacuum pyrolysis: Techniques and reactions

C Wentrup - Angewandte Chemie International Edition, 2017 - Wiley Online Library
Flash vacuum pyrolysis (FVP) had its beginnings in the 1940s and 1950s, mainly through
mass spectrometric detection of pyrolytically formed free radicals. In the 1960s many organic …

Gas-phase formation and spectroscopic characterization of the disubstituted cyclopropenylidenes c-C3 (C2H) 2, c-C3 (CN) 2, and c-C3 (C2H)(CN)

AR Flint, AG Watrous, BR Westbrook, DJ Patel… - Astronomy & …, 2023 - aanda.org
Aims. The detection of cC 3 HC 2 H and possible future detection of cC 3 HCN provide new
molecules for reaction chemistry in the dense interstellar medium (ISM) where RC 2 H and R …

Correlation between bonding, philicity and substituent effects in cyclopropenylidenes

PV Muhasina, AM Binoy, P Parameswaran - Computational and Theoretical …, 2021 - Elsevier
The electronic structure and bonding of cyclopropenylidenes with different substituents at
the olefinic position viz.,–H (1), electron-withdrawing groups (–CHO (2) and–COOH (3)) and …

Mass Spectrometry-Based Discovery of New Chemical Scaffold Rearrangement Ions: Aza-biphenylene as a Novel Potent Biradical Agent in Cancer Chemotherapy

YL Li, BW Zhou, J Cheng, F Zhang, J Zhang… - Analytical …, 2020 - ACS Publications
Discovery of a new drug is time-consuming, laborious, and expensive. Herein, a novel
integrative strategy for discovering potential new lead compounds has been developed …

Evaluation of the Lewis acidity of metal complexes using ESI mass spectrometry

R Zhang, PP Li, GG Gu… - European Journal of Mass …, 2020 - journals.sagepub.com
Metal complexes have extensive applications in catalysis, however, the efficient evaluation
of Lewis acidity of metal complexes is still a challenge. Herein, we report a method by using …

Carbenes and Nitrenes

MG Moloney - Organic Reaction Mechanisms· 2016: An annual …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Reviews Metal‐Free Carbenes–Structure
and Reactivity Metallated Carbenes–Structure and Reactivity Copper Rhodium Iridium …