Soot inception: Carbonaceous nanoparticle formation in flames

JW Martin, M Salamanca, M Kraft - Progress in Energy and Combustion …, 2022 - Elsevier
The route by which gas-phase molecules in hydrocarbon flames form condensed-phase
carbonaceous nanoparticles (incipient soot) is reviewed. These products of incomplete …

A review of terminology used to describe soot formation and evolution under combustion and pyrolytic conditions

HA Michelsen, MB Colket, PE Bengtsson, A D'anna… - ACS …, 2020 - ACS Publications
This review presents a glossary and review of terminology used to describe the chemical
and physical processes involved in soot formation and evolution and is intended to aid in …

Combustion chemistry of aromatic hydrocarbons

H **, W Yuan, W Li, J Yang, Z Zhou, L Zhao… - Progress in Energy and …, 2023 - Elsevier
Aromatic hydrocarbons are important components of petroleum-based transportation fuels,
biomass, coal, and solid waste, etc. The reaction kinetics of aromatic hydrocarbons largely …

Phenalenyl radical: Smallest polycyclic odd alternant hydrocarbon present in the graphene sheet

J Ahmed, SK Mandal - Chemical Reviews, 2022 - ACS Publications
Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

Soot formation during biomass gasification: A critical review

Q He, Q Guo, K Umeki, L Ding, F Wang, G Yu - Renewable and Sustainable …, 2021 - Elsevier
Biomass gasification is a promising technology in current and future low carbon energy
systems. Soot formation is a great technical challenge for the industrialization of biomass …

On the mechanism of soot nucleation

M Frenklach, AM Mebel - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The mechanism of carbon particulate (soot) inception has been a subject of numerous
studies and debates. The article begins with a critical review of prior proposals, proceeds to …

Combustion in the future: The importance of chemistry

K Kohse-Höinghaus - Proceedings of the Combustion Institute, 2021 - Elsevier
Combustion involves chemical reactions that are often highly exothermic. Combustion
systems utilize the energy of chemical compounds released during this reactive process for …

Portraits of soot molecules reveal pathways to large aromatics, five-/seven-membered rings, and inception through π-radical localization

LA Lieske, M Commodo, JW Martin, K Kaiser… - ACS …, 2023 - ACS Publications
Incipient soot early in the flame was studied by high-resolution atomic force microscopy and
scanning tunneling microscopy to resolve the atomic structure and orbital densities of single …

Engine, aftertreatment, fuel quality and non-tailpipe achievements to lower gasoline vehicle PM emissions: Literature review and future prospects

MM Maricq - Science of The Total Environment, 2023 - Elsevier
Spark ignition gasoline vehicles comprise most light duty vehicles worldwide. These
vehicles were not historically associated with PM emissions. This changed about 15 years …

Mechanism of the noncatalytic oxidation of soot using in situ transmission electron microscopy

M Gao, Y Jang, L Ding, Y Gao, S Dai, Z Dai… - Nature …, 2023 - nature.com
Soot generation is a major challenge in industries. The elimination of soot is particularly
crucial to reduce pollutant emissions and boost carbon conversion. The mechanisms for …