Coinage-metal-based cyclic trinuclear complexes with metal–metal interactions: theories to experiments and structures to functions

J Zheng, Z Lu, K Wu, GH Ning, D Li - Chemical Reviews, 2020 - ACS Publications
Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …

TADF: Enabling luminescent copper (i) coordination compounds for light-emitting electrochemical cells

CE Housecroft, EC Constable - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The last decade has seen a surge of interest in the emissive behaviour of copper (I)
coordination compounds, both neutral compounds that may have applications in organic …

The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

Sulfide boosting near-unity photoluminescence quantum yield of silver nanocluster

SS Zhang, S Havenridge, C Zhang… - Journal of the …, 2022 - ACS Publications
Silver nanoclusters have emerged as promising candidates for optoelectronic applications,
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …

Crystalline metal‐organic materials with thermally activated delayed fluorescence

Z Han, XY Dong, SQ Zang - Advanced Optical Materials, 2021 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) properties of crystalline metal‐organic
materials, mainly including small‐molecule metal–organic complexes, organic ligand …

Substituents' Effect on the Photophysics of Trinuclear Copper (I) and Silver (I) Pyrazolate–Phosphine Cages

KF Baranova, AA Titov, JR Shakirova… - Inorganic …, 2024 - ACS Publications
A series of structurally similar trinuclear macrocyclic copper (I) and silver (I) pyrazolate
complexes bearing various short-bite diphosphine R2PCH (R′) PR2 ligands are reported …

One-dimensional infinite chain Ag (i) complex with high quantum yield and TADF property: prepared by metal ion adjustment

ZZ Sun, FZ Hu, CJ Gao, WL Mou, G Wang, N Zhu… - …, 2023 - pubs.rsc.org
Four complexes with different metal ions were synthesized. The new Ag (I) complex [Ag
(bdppmapy)(Dpq)] CF3SO3 (AgDpq) with one-dimensional infinite chain exhibited excellent …

Revealing High-Lying Intersystem Crossing in Brightly Luminescent Cyclic Trinuclear CuI/AgI Complexes

LR **ng, Z Lu, M Li, J Zheng, D Li - The journal of physical …, 2020 - ACS Publications
The increased attention to luminescent copper (I) complexes, mostly mononuclear and
dinuclear ones, in the past few years was mainly due to the new pathways established in the …

A sublimable dinuclear cuprous complex showing selective luminescence vapochromism in the crystalline state

XW Chen, HL Yuan, LH He, JL Chen, SJ Liu… - Inorganic …, 2019 - ACS Publications
A new sublimable dicopper (I) complex bearing 1, 2-bis (diphenylphosphino) ethane and 5-
trifluoromethyl-3-(2′-pyridyl) pyrazolate ligands has been designed and synthesized, and …

Investigation of Luminescent Triplet States in Tetranuclear CuI Complexes: Thermochromism and Structural Characterization

P Boden, P Di Martino‐Fumo, JM Busch… - … A European Journal, 2021 - Wiley Online Library
To develop new and flexible CuI containing luminescent substances, we extend our
previous investigations on two metal‐centered species to four metal‐centered complexes …