Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries

G Assat, JM Tarascon - Nature Energy, 2018 - nature.com
Our increasing dependence on lithium-ion batteries for energy storage calls for continual
improvements in the performance of their positive electrodes, which have so far relied solely …

A Mechanistic Insight into the Oxygen Redox of Li‐Rich Layered Cathodes and their Related Electronic/Atomic Behaviors Upon Cycling

S Kang, D Choi, H Lee, B Choi, YM Kang - Advanced Materials, 2023 - Wiley Online Library
Li‐rich cathodes are extensively investigated as their energy density is superior to Li
stoichiometric cathode materials. In addition to the transition metal redox, this intriguing …

Chemical, structural, and electronic aspects of formation and degradation behavior on different length scales of Ni‐rich NCM and Li‐rich HE‐NCM cathode materials …

L de Biasi, B Schwarz, T Brezesinski… - Advanced …, 2019 - Wiley Online Library
In order to satisfy the energy demands of the electromobility market, both Ni‐rich and Li‐rich
layered oxides of NCM type are receiving much attention as high‐energy‐density cathode …

Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides

WE Gent, K Lim, Y Liang, Q Li, T Barnes, SJ Ahn… - Nature …, 2017 - nature.com
Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at
high potentials, thereby promising high energy densities for lithium-ion batteries. However …

Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes

G Assat, D Foix, C Delacourt, A Iadecola… - Nature …, 2017 - nature.com
Reversible anionic redox has rejuvenated the search for high-capacity lithium-ion battery
cathodes. Real-world success necessitates the holistic mastering of this electrochemistry's …