Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

CAP Goodwin, F Ortu, D Reta, NF Chilton, DP Mills - Nature, 2017 - nature.com
Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …

Synthesis and magnetism of neutral, linear metallocene complexes of terbium (II) and dysprosium (II)

CA Gould, KR McClain, JM Yu… - Journal of the …, 2019 - ACS Publications
The divalent metallocene complexes Ln (CpiPr5) 2 (Ln= Tb, Dy) were synthesized through
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …

Multifunctional Helicene‐Based Ytterbium Coordination Polymer Displaying Circularly Polarized Luminescence, Slow Magnetic Relaxation and Room Temperature …

K Dhbaibi, M Grasser, H Douib, V Dorcet… - Angewandte …, 2023 - Wiley Online Library
The combination of physical properties sensitive to molecular chirality in a single system
allows the observation of fascinating phenomena such as magneto‐chiral dichroism (MChD) …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2014 - Elsevier
A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Equatorially coordinated lanthanide single ion magnets

P Zhang, L Zhang, C Wang, S Xue… - Journal of the …, 2014 - ACS Publications
The magnetic relaxation dynamics of low-coordinate DyIII and ErIII complexes, namely three-
coordinate ones with an equatorially coordinated triangle geometry and five-coordinate …