Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Defective metal‐organic frameworks

S Dissegna, K Epp, WR Heinz, G Kieslich… - Advanced …, 2018 - Wiley Online Library
The targeted incorporation of defects into crystalline matter allows for the manipulation of
many properties and has led to relevant discoveries for optimized and even novel …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Removal of contaminants of emerging concern by metal-organic framework nanoadsorbents: A review

L Joseph, BM Jun, M Jang, CM Park… - Chemical Engineering …, 2019 - Elsevier
Over the last two decades, various contaminants of emerging concern (CECs), such as
endocrine disrupting compounds, along with pharmaceuticals and personal care products …

Pyrene-based metal organic frameworks: from synthesis to applications

FP Kinik, A Ortega-Guerrero, D Ongari… - Chemical Society …, 2021 - pubs.rsc.org
Pyrene is one of the most widely investigated aromatic hydrocarbons given to its unique
optical and electronic properties. Hence, pyrene-based ligands have been attractive for the …

Effective toluene adsorption over defective UiO-66-NH2: an experimental and computational exploration

X Shi, X Zhang, F Bi, Z Zheng, L Sheng, J Xu… - Journal of Molecular …, 2020 - Elsevier
In this thesis, defective UiO-66-NH 2 using cetyltrimethylammonium bromide (CTAB) as a
template was successfully synthesized. The toluene adsorption-desorption properties were …

Node-accessible zirconium MOFs

Z Lu, J Liu, X Zhang, Y Liao, R Wang… - Journal of the …, 2020 - ACS Publications
High-stability, zirconium-based metal–organic frameworks are attractive as heterogeneous
catalysts and as model supports for uniform arrays of subsequently constructed …

Catalytic transfer hydrogenation of furfural to furfuryl alcohol under mild conditions over Zr-MOFs: exploring the role of metal node coordination and modification

AH Valekar, M Lee, JW Yoon, J Kwak, DY Hong… - ACS …, 2020 - ACS Publications
The catalytic transfer hydrogenation (CTH) reaction is considered as a potential route for
upgrading bio-based carbonyls to their corresponding alcohols. Herein, a series of Zr-based …