Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R **, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Luminescent metal nanoclusters with aggregation-induced emission

N Goswami, Q Yao, Z Luo, J Li, T Chen… - The journal of physical …, 2016 - ACS Publications
Thiolate-protected metal nanoclusters (or thiolated metal NCs) have recently emerged as a
promising class of functional materials because of their well-defined molecular structures …

Quantum sized gold nanoclusters with atomic precision

H Qian, M Zhu, Z Wu, R ** - Accounts of chemical research, 2012 - ACS Publications
Gold nanoparticles typically have a metallic core, and the electronic conduction band
consists of quasicontinuous energy levels (ie spacing δ≪ k BT, where k BT is the thermal …

Understanding seed-mediated growth of gold nanoclusters at molecular level

Q Yao, X Yuan, V Fung, Y Yu, DT Leong… - Nature …, 2017 - nature.com
The continuous development of total synthesis chemistry has allowed many organic and
biomolecules to be produced with known synthetic history–that is, a complete set of step …

Quantum sized, thiolate-protected gold nanoclusters

R ** - Nanoscale, 2010 - pubs.rsc.org
The scientific study of gold nanoparticles (typically 1–100 nm) has spanned more than 150
years since Faraday's time and will apparently last longer. This review will focus on a special …

Recent advances in the synthesis and catalytic applications of ligand-protected, atomically precise metal nanoclusters

J Fang, B Zhang, Q Yao, Y Yang, J **e… - Coordination Chemistry …, 2016 - Elsevier
Due to their excellent catalytic properties under mild reaction conditions, well-defined,
nanosized noble metal catalysts have potential applications in the manufacture of fine …

Total Structure Determination of Thiolate-Protected Au38 Nanoparticles

H Qian, WT Eckenhoff, Y Zhu… - Journal of the American …, 2010 - ACS Publications
We report the total structure of Au38 (SC2H4Ph) 24 nanoparticles determined by single
crystal X-ray crystallography. This nanoparticle is based upon a face-fused Au23 …

Emerging chirality in nanoscience

Y Wang, J Xu, Y Wang, H Chen - Chemical Society Reviews, 2013 - pubs.rsc.org
Chirality in nanoscience may offer new opportunities for applications beyond the traditional
fields of chirality, such as the asymmetric catalysts in the molecular world and the chiral …

Synthesis, characterization, and application of ultrasmall nanoparticles

BH Kim, MJ Hackett, J Park, T Hyeon - Chemistry of Materials, 2014 - ACS Publications
Nanomaterials in the size range of 3–50 nm have received increased attention in the last
few decades because they exhibit physical properties that are intermediate to those of …