Deciphering the role of nickel in electrochemical organic oxidation reactions

S Ghosh, D Bagchi, I Mondal… - Advanced Energy …, 2024 - Wiley Online Library
Organic oxidation reactions (OORs) powered by renewable energy sources are gaining
importance as a favorable alternative to oxygen evolution reaction, with the promise of …

Selective oxidation using in situ-generated hydrogen peroxide

RJ Lewis, GJ Hutchings - Accounts of chemical research, 2023 - ACS Publications
Conspectus Hydrogen peroxide (H2O2) for industrial applications is manufactured through
an indirect process that relies on the sequential reduction and reoxidation of quinone …

Highly efficient catalytic production of oximes from ketones using in situ–generated H2O2

RJ Lewis, K Ueura, X Liu, Y Fukuta, TE Davies… - Science, 2022 - science.org
The ammoximation of cyclohexanone using preformed hydrogen peroxide (H2O2) is
currently applied commercially to produce cyclohexanone oxime, an important feedstock in …

Revealing the Crystal Facet Effect of Ceria in Pd/CeO2 Catalysts toward the Selective Oxidation of Benzyl Alcohol

L Zhang, R Chen, Y Tu, X Gong, X Cao, Q Xu, Y Li… - Acs …, 2023 - ACS Publications
Ceria is an excellent catalyst or support for various oxidation reactions due to its abundant
oxygen vacancies and strong metal–support interactions. In this study, ceria nanocrystals …

CsPbBr3/Polyoxometalate Composites for Selective Photocatalytic Oxidation of Benzyl Alcohol

Y Dong, Y Feng, Z Li, H Zhou, H Lv, GY Yang - ACS Catalysis, 2023 - ACS Publications
Selective oxidation of benzyl alcohols to the corresponding carbonyl compounds is of great
importance for providing versatile intermediates for the synthesis of pharmaceuticals and …

Development of MgIn2S4 Microflower-Embedded Exfoliated B-Doped gC3N4 Nanosheets: p–n Heterojunction Photocatalysts toward Photocatalytic Water Reduction and H2O …

L Acharya, G Swain, BP Mishra… - ACS Applied Energy …, 2022 - ACS Publications
In recent years, designing a highly efficient, cost-effective, and persistent photocatalyst to
annihilate world's major ongoing challenges has been a hot topic in the research …

Fast photocatalytic hydrogen peroxide generation by singlet oxygen-engaged sequential excitation energy and electron-transfer process

X Zeng, T Wang, Z Wang, M Tebyetekerwa, Y Liu… - ACS …, 2024 - ACS Publications
Sequential excitation energy and electron transfer (ET) are ubiquitous pathways for
converting solar energy to chemical energy in photosynthesis. Mimicking this unique …

Understanding the oxidative properties of nickel oxyhydroxide in alcohol oxidation reactions

PCM Laan, FJ de Zwart, EM Wilson, A Troglia… - ACS …, 2023 - ACS Publications
The NiOOH electrode is commonly used in electrochemical alcohol oxidations. Yet
understanding the reaction mechanism is far from trivial. In many cases, the difficulty lies in …

Tandem catalysis for selective oxidation of methane to oxygenates using oxygen over PdCu/zeolite

B Wu, T Lin, M Huang, S Li, J Li, X Yu… - Angewandte Chemie …, 2022 - Wiley Online Library
Selective oxidation of methane to oxygenates with O2 under mild conditions remains a great
challenge. Here we report a ZSM‐5 (Z‐5) supported PdCu bimetallic catalyst (PdCu/Z‐5) for …

Regulation of catalyst immediate environment enables acidic electrochemical benzyl alcohol oxidation to benzaldehyde

GS Shanker, A Ghatak, S Binyamin, R Balilty… - ACS …, 2024 - ACS Publications
Electrocatalytic alcohol oxidation in acid offers a promising alternative to the kinetically
sluggish water oxidation reaction toward low-energy H2 generation. However …