Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …

Alkyne hydrosilylation is one of the most efficient methods for the synthesis of alkenyl silicon
derivatives and has been a hot topic of research for decades. This short review summarizes …

Metal-catalyzed hydrosilylation of alkynes is an ideal atom-economic method to prepare
vinylsilanes that are useful reagents in the organic synthesis and silicone industry. Although …

While 1, 1-diboryl (gem-diboryl) compounds are valuable synthetic building blocks,
currently, related studies have mainly focused on those 1, 1-diboryl alkanes without a hetero …

A practical and efficient method to access polysubstituted aryl sulfides has been discovered
via a Lewis acid-catalyzed reaction between alkynyl sulfide and 2-pyrone, involving a Diels …

While 1, 2-addition represents the most common mode of alkyne hydroboration, herein we
describe a new 1, 1-hydroboration mode. It is the first demonstration of gem-(H, B) addition …

Silylalkenes are important synthetic intermediates to substituted alkenes and silicon
materials and can be directly obtained by the catalytic selective hydrosilylation of alkynes. In …

A photochemical dual‐catalytic cross‐coupling to form alkynyl sulfides via C (sp)− S bond
formation is described. The cross‐coupling of thiols and bromoalkynes is promoted by a …

Although hydroboration of simple ketones and alkynes have been well-established, little is
known about the unique hydroboration reactivity for ynones, a family of important building …

A Rh2 (OAc) 4/XantPhos ((9, 9-dimethyl-9H-xanthene-4, 5-diyl) bis (diphenylphosphane))
catalyzed regio-and stereoselective hydrosilylation of alkynes with various tertiary silanes in …