Metal-catalyzed decarboxylative C–H functionalization

Y Wei, P Hu, M Zhang, W Su - Chemical Reviews, 2017 - ACS Publications
C–H bond activation and decarboxylation are two significant processes in organic synthesis.
The combination of these processes provides a novel synthetic strategy, that is …

Metal-catalyzed C–H functionalization involving isocyanides

B Song, B Xu - Chemical Society Reviews, 2017 - pubs.rsc.org
Isocyanides have a broad range of applications in multicomponent reactions such as
Passerini and Ugi processes. Recent advances in metal catalysis have tremendously …

Wonderful fusion of organofluorine chemistry and decarboxylation strategy

P **ao, X Pannecoucke, JP Bouillon… - Chemical Society …, 2021 - pubs.rsc.org
Decarboxylation strategy has been emerging as a powerful tool for the synthesis of fluorine-
containing organic compounds that play important roles in various fields such as …

Supramolecular complex catalyzed green synthesis of 9-(2-Ethylhexyl) carbazole: Structural, optical and DFT investigations

P Behera, TJ Jose, DS Ramakrishna… - Journal of Molecular …, 2024 - Elsevier
Green chemical principles such as (a) bio-renewable solvent utilization,(b) phase transfer
catalysis (c) coloumn chromatography free methodologies, and (d) mild reaction conditions …

Electrooxidative tandem cyclization of activated alkynes with sulfinic acids to access sulfonated indenones

J Wen, W Shi, F Zhang, D Liu, S Tang, H Wang… - Organic …, 2017 - ACS Publications
An electrooxidative direct arylsulfonlylation of ynones with sulfinic acids via a radical tandem
cyclization strategy has been developed for the construction of sulfonated indenones under …

The direct C–H difluoromethylation of heteroarenes based on the photolysis of hypervalent iodine (III) reagents that contain difluoroacetoxy ligands

R Sakamoto, H Kashiwagi, K Maruoka - Organic Letters, 2017 - ACS Publications
In this letter, an efficient method for the photolytic generation of difluoromethyl radicals from
[bis (difluoroacetoxy) iodo] benzene reagents is described. The present approach enables …

Transition-metal-free decarboxylative C3-difluoroarylmethylation of quinoxalin-2 (1 H)-ones with α, α-difluoroarylacetic acids

G Hong, J Yuan, J Fu, G Pan, Z Wang, L Yang… - Organic Chemistry …, 2019 - pubs.rsc.org
A facile transition-metal-free decarboxylative radical coupling reaction of α, α-
difluoroarylacetic acids with quinoxalin-2 (1H)-ones has been developed. This methodology …

Copper-Catalyzed C–H Difluoroalkylations and Perfluoroalkylations of Alkenes and (Hetero) arenes

X Wang, S Zhao, J Liu, D Zhu, M Guo, X Tang… - Organic …, 2017 - ACS Publications
A general and facile synthetic method for C (sp2)–H difluoroalkylations and
perfluoroalkylations of alkenes and (hetero) arenes with commercially available fluoroalkyl …

The ortho‐Difluoroalkylation of Aryliodanes with Enol Silyl Ethers: Rearrangement Enabled by a Fluorine Effect

X Huang, Y Zhang, C Zhang, L Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
Presented herein is an intriguing effect of fluorine, and it allows difluoroenol silyl ethers to
couple with aryliodanes in a redox‐neutral manner to afford ortho‐iodo difluoroalkylated …

Visible-Light-Induced Cascade Cyclization of 1-Acryloyl-2-cyanoindole: Access of Difluoroalkylated Pyrrolo[1,2-a]indolediones

J Yuan, L Shen, N Guo, Y Yin, P Yang… - The Journal of …, 2023 - ACS Publications
An effective method for accessing diverse difluoroalkylated pyrrolo [1, 2-a] indolediones via
visible-light-induced PhI (OAc) 2-promoted cascade difluoroalkylation/cyclization reaction …