Catalytic asymmetric dearomatization reactions

CX Zhuo, W Zhang, SL You - … Chemie International Edition, 2012 - Wiley Online Library
This Review summarizes the development of catalytic asymmetric dearomatization (CADA)
reactions. The CADA reactions discussed herein include oxidative dearomatization …

Dearomatization strategies in the synthesis of complex natural products

SP Roche, JA Porco Jr - Angewandte Chemie International …, 2011 - Wiley Online Library
Evolution in the field of the total synthesis of natural products has led to exciting
developments over the last decade. Numerous chemoselective and enantioselective …

Catalytic enantioselective Diels–Alder reactions: methods, mechanistic fundamentals, pathways, and applications

EJ Corey - Angewandte Chemie International Edition, 2002 - Wiley Online Library
Conference of 2001, and describes research by our group on the development and
understanding of enantioselective versions of the Diels±Alder reactions. The elements of …

BINOL: a versatile chiral reagent

JM Brunel - Chemical reviews, 2005 - ACS Publications
BINOL: A Versatile Chiral Reagent | Chemical Reviews Recently Viewedclose modal ACS ACS
Publications C&EN CAS Find my institution Log In ACS Publications. Most Trusted. Most Cited …

Hypervalent iodine-mediated phenol dearomatization in natural product synthesis

L Pouységu, D Deffieux, S Quideau - Tetrahedron, 2010 - Elsevier
The richness of the chemistry of phenols is quite remarkable when one realizes that it is
simply the presence of a hydroxy group on a benzene ring that renders this otherwise quasi …

Cyclohexadienone ketals and quinols: four building blocks potentially useful for enantioselective synthesis

D Magdziak, SJ Meek, TRR Pettus - Chemical reviews, 2004 - ACS Publications
1383 Chem. Rev. 2004, 104, 1383− 1429 10.1021/cr0306900 CCC: $48.50© 2004
American Chemical Society Published on Web 03/10/2004 metric preparation of this …

The first general enantioselective catalytic Diels− Alder reaction with simple α, β-unsaturated ketones

AB Northrup, DWC MacMillan - Journal of the American Chemical …, 2002 - ACS Publications
The first general approach to enantioselective catalysis of the Diels− Alder reaction with
simple ketone dienophiles has been accomplished. The use of iminium catalysis has …

Asymmetric direct/stepwise dearomatization reactions involving hypervalent iodine reagents

R Kumar, FV Singh, N Takenaga… - Chemistry–An Asian …, 2022 - Wiley Online Library
A remarkable growth in hypervalent iodine‐mediated oxidative transformations as
stoichiometric reagents as well as catalysts has been well‐documented due to their …

In the arena of enantioselective synthesis, titanium complexes wear the laurel wreath

DJ Ramon, M Yus - Chemical reviews, 2006 - ACS Publications
Asymmetry is ubiquitous in every part of Nature1 and has a great impact in many fields, not
only in chemistry but also even in arts. In the pharmaceutical area, asymmetry plays an …

Update 1 of: BINOL: a versatile chiral reagent

JM Brunel - Chemical reviews, 2007 - ACS Publications
Over the last 20 years an explosive growth of the research in the field of asymmetric
synthesis has occurred. 1-9 The aim of enantioselective synthesis, or catalysis, is to produce …