NHCs in main group chemistry
V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …
1990s, these divalent carbon species have become a common and available class of …
N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …
research fields, and it is not possible to imagine modern transition metal and main group …
Dinuclear gold (i) complexes: from bonding to applications
TACA Bayrakdar, T Scattolin, X Ma… - Chemical Society …, 2020 - pubs.rsc.org
The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …
Enhancing biocatalysis of a MXene-based biomimetic plasmonic assembly for targeted cancer treatments in NIR-II biowindow
Biocatalysis-based nanomedicines have attracted considerable attention in the field of
biomedicine. However, improving catalytic activity as a prerequisite for the therapeutic effect …
biomedicine. However, improving catalytic activity as a prerequisite for the therapeutic effect …
The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes)PFPh2][B(C6F5)4]2
The dicationic imidazolium‐phosphonium salt [(SIMes) PFPh2][B (C6F5) 4] 2 has been
prepared and shown to exhibit remarkable Lewis acidity in stoichiometric reactions and …
prepared and shown to exhibit remarkable Lewis acidity in stoichiometric reactions and …
Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds
L Dostál - Coordination Chemistry Reviews, 2017 - Elsevier
The chemistry of low-valent main group compounds represents one of the most exciting and
quickly develo** areas in the field of organometallic and organoelement chemistry. In this …
quickly develo** areas in the field of organometallic and organoelement chemistry. In this …
N‐Heterocyclic Carbene–Phosphinidyne Transition Metal Complexes
The N‐heterocyclic carbene–phosphinidene adduct IPr PSiMe3 is introduced as a synthon
for the preparation of terminal carbene–phosphinidyne transition metal complexes of the …
for the preparation of terminal carbene–phosphinidyne transition metal complexes of the …
Bipyridine complexes of E 3+(E= P, As, Sb, Bi): strong Lewis acids, sources of E (OTf) 3 and synthons for Ei and Ev cations
Triflate salts of trications [(bipy) 2E] 3+([6E][OTf] 3) and [(tbbipy) 2E] 3+([6′ E][OTf] 3)(bipy=
2, 2′-bipyridine, tbbipy= 4, 4′-di-tbutyl-2, 2′-bipyridine; E= P, As, Sb, Bi) have been …
2, 2′-bipyridine, tbbipy= 4, 4′-di-tbutyl-2, 2′-bipyridine; E= P, As, Sb, Bi) have been …
Normal‐to‐Abnormal NHC Rearrangement of AlIII, GaIII, and InIII Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2 Activation
G Schnee, O Nieto Faza, D Specklin… - … A European Journal, 2015 - Wiley Online Library
The present contribution reports experimental and theoretical mechanistic investigations on
a normal‐to‐abnormal (C2‐to‐C4‐bonded) NHC rearrangement processes occurring with …
a normal‐to‐abnormal (C2‐to‐C4‐bonded) NHC rearrangement processes occurring with …
N‐Heterocyclic Carbene–Phosphinidene Complexes of the Coinage Metals
A Doddi, D Bockfeld, A Nasr… - … A European Journal, 2015 - Wiley Online Library
Coinage metal complexes of the N‐heterocyclic carbene–phosphinidene adduct IPr⋅ PPh
(IPr= 1, 3‐bis (2, 6‐diisopropylphenyl) imidazolin‐2‐ylidene) were prepared by its reaction …
(IPr= 1, 3‐bis (2, 6‐diisopropylphenyl) imidazolin‐2‐ylidene) were prepared by its reaction …