Real-space grids and the Octopus code as tools for the development of new simulation approaches for electronic systems

X Andrade, D Strubbe, U De Giovannini… - Physical Chemistry …, 2015 - pubs.rsc.org
Real-space grids are a powerful alternative for the simulation of electronic systems. One of
the main advantages of the approach is the flexibility and simplicity of working directly in real …

Two-electron Rabi oscillations in real-time time-dependent density-functional theory

BF Habenicht, NP Tani, MR Provorse… - The Journal of chemical …, 2014 - pubs.aip.org
We investigate the Rabi oscillations of electrons excited by an applied electric field in
several simple molecular systems using time-dependent configuration interaction (TDCI) …

Origin of static and dynamic steps in exact Kohn-Sham potentials

MJP Hodgson, JD Ramsden, RW Godby - Physical Review B, 2016 - APS
Knowledge of exact properties of the exchange-correlation (xc) functional is important for
improving the approximations made within density functional theory. Features such as steps …

Exact thermal density functional theory for a model system: Correlation components and accuracy of the zero-temperature exchange-correlation approximation

JC Smith, A Pribram-Jones, K Burke - Physical Review B, 2016 - APS
Thermal density functional theory calculations often use the Mermin-Kohn-Sham scheme,
but employ ground-state approximations to the exchange-correlation (XC) free energy. In the …

Kinetic and interaction components of the exact time-dependent correlation potential

K Luo, JI Fuks, ED Sandoval, P Elliott… - The Journal of chemical …, 2014 - pubs.aip.org
The exact exchange-correlation (xc) potential of time-dependent density functional theory
has been shown to have striking features. For example, step and peak features are …

Self-consistent density-functional embedding: A novel approach for density-functional approximations

U Mordovina, TE Reinhard, I Theophilou… - Journal of chemical …, 2019 - ACS Publications
In the present work, we introduce a self-consistent density-functional embedding technique,
which leaves the realm of standard energy-functional approaches in density functional …

Time-dependent density functional theory beyond Kohn–Sham Slater determinants

JI Fuks, SEB Nielsen, M Ruggenthaler… - Physical Chemistry …, 2016 - pubs.rsc.org
When running time-dependent density functional theory (TDDFT) calculations for real-time
simulations of non-equilibrium dynamics, the user has a choice of initial Kohn–Sham state …

Nonlinear light absorption in many-electron systems excited by an instantaneous electric field: a non-perturbative approach

A Guandalini, C Cocchi, S Pittalis, A Ruini… - Physical Chemistry …, 2021 - pubs.rsc.org
Applications of low-cost non-perturbative approaches in real time, such as time-dependent
density functional theory, for the study of nonlinear optical properties of large and complex …

Inverting the Kohn–Sham equations with physics-informed machine learning

V Martinetto, K Shah, A Cangi… - … Learning: Science and …, 2024 - iopscience.iop.org
Electronic structure theory calculations offer an understanding of matter at the quantum
level, complementing experimental studies in materials science and chemistry. One of the …

Universal steps in quantum dynamics with time-dependent potential-energy surfaces: Beyond the Born-Oppenheimer picture

G Albareda, A Abedi, I Tavernelli, A Rubio - Physical Review A, 2016 - APS
It was recently shown [G. Albareda, Phys. Rev. Lett. 113, 083003 (2014)] PRLTAO 0031-
9007 10.1103/PhysRevLett. 113.083003 that within the conditional decomposition approach …