The hydrated electron, e–(aq), has attracted much attention as a central species in radiation
chemistry. However, much less is known about e–(aq) at the water/air surface, despite its …

Charge-transfer-to-solvent states in aqueous halides are ideal systems for studying the
electron-transfer dynamics to the solvent involving a complex interplay between electronic …

Addressing the economic and environmental challenges posed by non-target losses
throughout the pesticide life cycle necessitates a simple, yet effective strategy. In this work, a …

Even though single hydrated electrons (e hyd–'s) are stable in liquid water, two hydrated
electrons can bimolecularly react with water to create H2 and hydroxide: e hyd–+ e hyd–+ …

A primary means to generate hydrated electrons in laboratory experiments is excitation to
the charge-transfer-to-solvent (CTTS) state of a solute such as I–(aq), but this initial step in …

Mixed quantum-classical molecular dynamics simulations have been important tools for
studying the hydrated electron. They generally use a one-electron pseudopotential to …

Reactions of the hydrated electron with a wide variety of substrates have been found to
exhibit unusually similar activation energies in a manner incompatible with Marcus electron …

The dynamics of (few) electrons dissolved in an ionic fluid—as when a small amount of
metal is added to a solution while upholding its electronic insulation—manifests interesting …

In the radiation chemistry of water, two hydrated electrons (e hyd−) can react to form H2 and
OH–. Experiments and simulations suggest that this reaction occurs through a mechanism …

Experiments have shown that in the presence of electrolytes, the hydrated electron's
absorption spectrum experiences a blue shift whose magnitude depends on both the salt …