Modular Synthesis of a Tridecasaccharide Motif of Bacteroides vulgatus Lipopolysaccharides against Inflammatory Bowel Diseases through an Orthogonal One‐Pot …
Y Zhang, L Wang, Q Zhou, Z Li, D Li… - Angewandte Chemie …, 2023 - Wiley Online Library
Lipopolysaccharides from Bacteroides vulgatus represent interesting targets for the
treatment of inflammatory bowel diseases. However, efficient access to long, branched and …
treatment of inflammatory bowel diseases. However, efficient access to long, branched and …
[HTML][HTML] Progress in Kdo-glycoside chemistry
P Kosma - Tetrahedron letters, 2016 - Elsevier
Glycosylation chemistry of 3-deoxy-d-manno-oct-2-ulosonic acid units has been
considerably developed within the last decade. This review covers major achievements with …
considerably developed within the last decade. This review covers major achievements with …
Chemical Synthesis and Antigenic Evaluation of Inner Core Oligosaccharides from Acinetobacter baumannii Lipopolysaccharide
XY Zhou, LX Li, Z Zhang, SC Duan… - Angewandte Chemie …, 2022 - Wiley Online Library
Acinetobacter baumannii is currently posing a serious threat to global health.
Lipopolysaccharide (LPS) is a potent virulence factor of pathogenic Gram‐negative bacteria …
Lipopolysaccharide (LPS) is a potent virulence factor of pathogenic Gram‐negative bacteria …
Stereodirecting Effect of C5-Carboxylate Substituents on the Glycosylation Stereochemistry of 3-Deoxy-d-manno-oct-2-ulosonic Acid (Kdo) Thioglycoside Donors …
W Huang, YY Zhou, XL Pan, XY Zhou… - Journal of the …, 2018 - ACS Publications
The stereodirecting effect of C5-ester functions on the glycosylation stereoselectivity of 3-
deoxy-d-manno-oct-2-ulosonic acid (Kdo) ethyl thioglycoside donors is presented. The …
deoxy-d-manno-oct-2-ulosonic acid (Kdo) ethyl thioglycoside donors is presented. The …
Conformationally constrained glycosyl donors as tools to control glycosylation outcomes
RA Jeanneret, SE Johnson… - The Journal of Organic …, 2020 - ACS Publications
The stereoselective synthesis of oligosaccharides remains one of the biggest challenges in
carbohydrate chemistry. Many factors, including reaction conditions and the type of glycosyl …
carbohydrate chemistry. Many factors, including reaction conditions and the type of glycosyl …
Full Stereocontrol in α-Glycosidation of 3-Deoxy-d-manno-2-octulosonic Acid (Kdo) Using Macrobicyclic Glycosyl Donors
S Hamajima, N Komura, HN Tanaka, A Imamura… - Organic …, 2022 - ACS Publications
We describe a method for the α-selective glycosidation of 3-deoxy-d-manno-2-octulosonic
acid (Kdo) using a macrobicyclic Kdo donor as the precursor of a bridgehead oxocarbenium …
acid (Kdo) using a macrobicyclic Kdo donor as the precursor of a bridgehead oxocarbenium …
α-Stereoselective 3-Deoxy-d-manno-oct-2-ulosonoic Acid (Kdo) O-Glycosylation with a p-Toluenethioglycoside Donor by the (p-Tol)2SO/Tf2O Preactivation …
J Zhang, X Gao, S Liu, Z Geng, L Chang, Y Liu… - Organic …, 2023 - ACS Publications
A convenient and efficient approach was developed to synthesize α-Kdo O-glycosides
based on the Tf2O/(p-Tol) 2SO preactivation strategy using peracetylated Kdo thioglycoside …
based on the Tf2O/(p-Tol) 2SO preactivation strategy using peracetylated Kdo thioglycoside …
Stereocontrolled Synthesis of α‐3‐Deoxy‐d‐manno‐oct‐2‐ulosonic Acid (α‐Kdo) Glycosides Using C3‐p‐Tolylthio‐Substituted Kdo Donors: Access to Highly …
A Sun, Z Li, Y Wang, S Meng, X Zhang… - Angewandte …, 2024 - Wiley Online Library
Deoxy‐d‐manno‐oct‐2‐ulosonic acid (Kdo) is an eight‐carbon monosaccharide found
widely in bacterial lipopolysaccharides (LPSs) and capsule polysaccharides (CPSs). We …
widely in bacterial lipopolysaccharides (LPSs) and capsule polysaccharides (CPSs). We …
Investigation of the protection of the C4 hydroxyl group in macrobicyclic Kdo donors
S Hamajima, N Komura, HN Tanaka, A Imamura… - Molecules, 2022 - mdpi.com
Chemical synthesis of 3-deoxy-d-manno-2-octulosonic acid (Kdo)-containing glycans, such
as bacterial lipopolysaccharides (LPSs) and capsular polysaccharides (CPSs), is in high …
as bacterial lipopolysaccharides (LPSs) and capsular polysaccharides (CPSs), is in high …
Stereocontrolled Synthesis of the Equatorial Glycosides of 3-Deoxy-d-manno-oct-2-ulosonic Acid: Role of Side Chain Conformation
P Ngoje, D Crich - Journal of the American Chemical Society, 2020 - ACS Publications
The pseudosymmetric relationship of the bacterial sialic acid, pseudaminic acid, and 3-
deoxy-d-manno-oct-2-ulosonic acid (KDO) affords the hypothesis that suitably protected …
deoxy-d-manno-oct-2-ulosonic acid (KDO) affords the hypothesis that suitably protected …