Proton-Coupled Electron Transfer at the Pu5+/4+ Couple
KS Otte, JE Niklas, CM Studvick… - Journal of the …, 2024 - ACS Publications
The synthesis and solution and solid-state characterization of [Pu4+ (NPC) 4], 1-
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …
Lanthanide-based photocatalysts for CO2 conversion: Are they a better choice for realizing sustainability?
L Li, Z Wang, L Zhao, H Liu, Y Li - Coordination Chemistry Reviews, 2025 - Elsevier
Employing photocatalysis to diminish CO 2 concentrations when exposed to visible
spectrum illumination, converting it into energy materials and chemical products, is an …
spectrum illumination, converting it into energy materials and chemical products, is an …
Preparation of neptunyl and plutonyl acetates to access nonaqueous transuranium coordination chemistry
Uranyl diacetate dihydrate is a useful reagent for the preparation of uranyl (UO22+)
coordination complexes, as it is a well-defined stoichiometric compound featuring …
coordination complexes, as it is a well-defined stoichiometric compound featuring …
Employing a template synthesis to access diastereopure Np (iv) and U (iv) complexes and analysis of their 5f orbitals in bonding
Development of new synthetic methods to employ with transuranium organometallic
complexes will help further the field and may provide a stronger understanding of their …
complexes will help further the field and may provide a stronger understanding of their …
Potassium–telluroether interactions: structural characterisation and computational analysis
Dissolution of the potassium complex [K (ATe2Tripp2)(dme) 2](1-Te) in THF, layering with
hexanes, and cooling to− 30° C afforded X-ray quality crystals of [K (ATe2Tripp2)(THF) 3](2 …
hexanes, and cooling to− 30° C afforded X-ray quality crystals of [K (ATe2Tripp2)(THF) 3](2 …
Advancing the understanding of M–O covalency in isostructural M–OSiMe 3 (M= Ce, Th, U) complexes
K Liu, X Chi, Y Guo, K Hu, L Mei, J Yu… - New Journal of Chemistry, 2024 - pubs.rsc.org
The covalency of f-block elements is particularly important for us to understand the bonding
nature of their chemical bonds. In this work, a series of isostructural 4f and 5f complexes:[M …
nature of their chemical bonds. In this work, a series of isostructural 4f and 5f complexes:[M …
Correlation Between NMR Coupling Constants and σ‐Donating Properties of N‐Heterocyclic Carbenes and Their Derivatives
Is the 1jc− h coupling constant for protonated carbene a relevant measure of its σ‐donation
ability? This paper addresses this question by comparing calculated 1jc− h values with …
ability? This paper addresses this question by comparing calculated 1jc− h values with …
Exploring the antimicrobial potential of new selenium- N-heterocyclic carbene complexes and their benzimidazolium salts: synthesis, characterization, biological …
The present work, describes the synthesis and antimicrobial evaluation of new selenium-
NHC adducts (3a-e) and their corresponding benzimidazolium salts (2a-e). Specific …
NHC adducts (3a-e) and their corresponding benzimidazolium salts (2a-e). Specific …
How do NMR coupling constants correlate with σ-donation in NHCs and their derivatives?
R Gupta, G Frison - 2024 - chemrxiv.org
Is the 1JC-H coupling constant for protonated carbene a relevant measure of its σ-donation
ability? This paper addresses this question by comparing calculated 1JC-H values with …
ability? This paper addresses this question by comparing calculated 1JC-H values with …