The main contributions in the field of first-row transition-metal-catalyzed (base-metal-
catalyzed) carbonylative transformations have been summarized and discussed. The …

Dinuclear PdI complexes have found widespread applications as diverse catalysts for a
multitude of transformations. Initially their ability to function as pre‐catalysts for low …

Light-driven strategies that enable the chemoselective activation of a specific bond in
multifunctional systems are comparatively underexplored in comparison to transition-metal …

Owing to the unknown correlation of a metal's ligand and its resulting preferred speciation in
terms of oxidation state, geometry, and nuclearity, a rational design of multinuclear catalysts …

We report the triply selective and sequential diversification of a single Csp3 carbon carrying
Cl, Bpin and GeEt3 for the modular and programmable construction of sp3‐rich molecules …

Site-selective dihalogenated heteroarene cross-coupling with organometallic reagents
usually occurs at the halogen proximal to the heteroatom, enabled by intrinsic relative …

This report describes the chemoselective coupling of polyfluoroarenes with aryl germanes in
the presence of aromatic C–I, C–Br, C–Cl, C–OTf, and C–SiMe3 groups, as well as …

Selective C–C couplings are powerful strategies for the rapid and programmable
construction of bi‐or multiaryls. To this end, the next frontier of synthetic modularity will likely …

Palladium catalysts have become central to modern organic synthesis, particularly in the
context of cross‐coupling reactions to form C− C and C‐heteroatom bonds. The …

Chemodivergent cross‐couplings are those in which either one of two (or more) potentially
reactive functional groups can be made to react based on choice of conditions. In particular …