Hydrosilylation of alkenes is an important reaction for the production of organosilicon
compounds such as industrially important silicones and silane coupling agents. To …

Late transition metal complexes with metal-silicon or metal-germanium σsingle bondbond
show the chemical properties that could not be found for the complexes with metal-carbon …

Diphosphino-boryl-based PBP pincer platinum thiolate complexes,[Pt (SR){B (NCH2PtBu2)
2-1, 2-C6H4}](R= H, 1a; Ph, 1b), and benzene-based bisphosphinite POCOP pincer …

Cobalt POCOP pincer complexes {κP, κC, κP-2, 6-(i Pr2PO) 2C6H3} Co (PMe3) 2 (1) and
{κP, κC, κP-2, 6-(i Pr2PO) 2-4-NMe2-C6H2} Co (PMe3) 2 (2) have been synthesized via C …

Bis (phosphinite) pincer platinum hydride complexes,[2, 6‐(R2PO) 2C6H3] PtH (R= tBu, iPr),
were synthesized, characterized and applied to the hydrosilylation of aldehydes and …

We report the reactions of an iminophosphonamido-silylene (1) with different palladium
complexes. The reaction of 1 with [Pd (PPh3) 4] furnished a homoleptic tris (silylene) …

A hexanuclear palladium cluster supported by two silylene units was readily linked by
molecules of a linear ditopic isocyanide to afford a coordination polymer that retained the …

The terphenyl amido stannylene‐NHC adducts, HMDS (MesTer) Sn (NHC),(MesTer= 2, 6‐
Mes2C6H3, Mes= 2, 4, 6‐Me3‐C6H2, HMDS= N (SiMe3) 2, NHC= IMe4, IEt, IMe4= 1, 3, 4, 5 …

A planar tetranuclear palladium cluster was obtained from the reaction of a cyclotetrasilane
with [Pd (CNtBu) 2] 3. Single‐crystal X‐ray diffraction analysis and DFT calculations …

Abstract Fe‐iminobipyridine complexes ((RBPIAr, R′) FeBr2, RBPIAr, R′= iminobipyridine
derivatives) were found to exhibit good catalytic activity for hydrosilylation of ketones. The …