Nature of carbon black reinforcement of rubber: Perspective on the original polymer nanocomposite

CG Robertson, NJ Hardman - Polymers, 2021 - mdpi.com
Adding carbon black (CB) particles to elastomeric polymers is essential to the successful
industrial use of rubber in many applications, and the mechanical reinforcing effect of CB in …

Recent advances in the theory of filler networking in elastomers

G Heinrich, M Klüppel - Filled elastomers drug delivery systems, 2002 - Springer
The viscoelastic properties of (mostly carbon black) filled elastomers are reviewed with
emphasis on the strain-dependence of the complex dynamic modulus (Payne effect) …

50th Anniversary Perspective: Are Polymer Nanocomposites Practical for Applications?

SK Kumar, BC Benicewicz, RA Vaia, KI Winey - Macromolecules, 2017 - ACS Publications
The field of polymer nanocomposites has been at the forefront of research in the polymer
community for the past few decades. Foundational work published in Macromolecules …

How nano are nanocomposites?

DW Schaefer, RS Justice - Macromolecules, 2007 - ACS Publications
Composite materials loaded with nanometer-sized reinforcing fillers are widely believed to
have the potential to push polymer mechanical properties to extreme values. Realization of …

Advances in layered double hydroxide (LDH)-based elastomer composites

D Basu, A Das, KW Stöckelhuber… - Progress in Polymer …, 2014 - Elsevier
This article reviews the advances in layered double hydroxide (LDH) materials and the
synthesis of LDH-based elastomer composites. The potential of tuning the structure of LDH …

The role of disorder in filler reinforcement of elastomers on various length scales

M Klüppel - Filler-reinforced elastomers scanning force microscopy, 2003 - Springer
The chapter considers the disordered nature of filler networks on different length scales and
relates it to the specific reinforcing properties of active fillers in elastomer composites. On …

Covalent bond scission in the Mullins effect of a filled elastomer: real‐time visualization with mechanoluminescence

JM Clough, C Creton, SL Craig… - Advanced Functional …, 2016 - Wiley Online Library
Strain‐induced light emission from mechanoluminescent cross‐linkers in silica‐filled poly
(dimethylsiloxane) demonstrates that covalent bond scission contributes significantly to …

[KSIĄŻKA][B] Reinforcement of polymer nano-composites: theory, experiments and applications

TA Vilgis, G Heinrich, M Klüppel - 2009 - books.google.com
Reinforced rubber allows the production of passenger car tires with improved rolling
resistance and wet grip. This book provides in-depth coverage of the physics behind …

Multiscale filler structure in simplified industrial nanocomposite silica/SBR systems studied by SAXS and TEM

GP Baeza, AC Genix, C Degrandcourt… - …, 2013 - ACS Publications
Simplified silica (Zeosil 1165 MP) and SBR (140k carrying silanol end-groups)
nanocomposites have been formulated by mixing of a reduced number of ingredients with …

Molecular mechanisms of failure in polymer nanocomposites

D Gersappe - Physical review letters, 2002 - APS
Molecular dynamics simulations of polymers reinforced with nanoscopic filler particles
reveal the mechanisms by which nanofillers improve the toughness of the material. We find …