This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

We report the first homoleptic Mo0 complex with bidentate isocyanide ligands, which
exhibits metal‐to‐ligand charge transfer (3MLCT) luminescence with quantum yields and …

The isomerization of terminal alkenes is an important and atom-economical process that
accesses otherwise difficult-to-prepare internal alkenes via a precious metal (eg, ruthenium …

A putative lipopeptide biosynthetic gene cluster is conserved in many species of
Actinobacteria, including Mycobacterium tuberculosis and M. marinum, but the specific …

In the structures of the isostructural cocrystals [CuI3 (CNXyl) 3]· CHX3 (X= Br, I), two adjacent
CuI-bound isocyanide groups, whose carbon lone pairs are blocked by ligation, exhibit …

Boron monofluoride (BF) is a diatomic molecule with 10 valence electrons, isoelectronic to
carbon monoxide (CO). Unlike CO, which is a stable molecule at room temperature and …

Despite their proposed accumulation at the Fe sites of the FeMo-cofactor of MoFe-
nitrogenase, the presence of hydride ligands in molecular model systems capable of the …

Es wird der erste homoleptische Mo0‐Komplex mit zweizähnigen Isocyanidliganden
vorgestellt, der 3MLCT‐Lumineszenz mit Quantenausbeuten und Lebenszeiten …

Previously, we reported the synthesis of Ti [N (o-(NCH2P (i Pr) 2) C6H4) 3] and the Fe–Ti
complex, FeTi [N (o-(NCH2P (i Pr) 2) C6H4) 3], abbreviated as TiL (1), and FeTiL (2) …

The encumbered tetraisocyanide dianion Na2 [Fe (CNAr) 4] reacts with two molecules of
CO2 to effect reductive disproportionation to CO and carbonate ([CO3] 2−). When the …