Supported gold nanoparticles as catalysts for the oxidation of alcohols and alkanes

SAC Carabineiro - Frontiers in Chemistry, 2019 - frontiersin.org
Supporting gold nanoparticles have shown to be extremely active for many industrially
important reactions, including oxidations. Two representative examples are the oxidation of …

Advances and future trends in selective oxidation catalysis: A critical review

GD Yadav, RK Mewada, DP Wagh… - Catalysis Science & …, 2022 - pubs.rsc.org
Selective or partial oxidation of organic compounds is one of the most important chemical
processes due to its industrial significance and the intermediates formed in oxidation …

Tris (pyrazol-1-yl) methane metal complexes for catalytic mild oxidative functionalizations of alkanes, alkenes and ketones

LM Martins, AJL Pombeiro - Coordination Chemistry Reviews, 2014 - Elsevier
This work concerns recent advances (since 2005) in the oxidative functionalization of
alkanes, alkenes and ketones, under mild conditions, catalyzed by homoscorpionate tris …

Gold nanoparticles supported on carbon materials for cyclohexane oxidation with hydrogen peroxide

SAC Carabineiro, L Martins, M Avalos-Borja… - Applied Catalysis A …, 2013 - Elsevier
Abstract Gold (1 wt.%) was loaded on several types of carbon materials (activated carbon,
polymer based carbon xerogels, multi-walled carbon nanotubes, nanodiamonds …

Vanadium (V) complexes with substituted 1, 5-bis (2-hydroxybenzaldehyde) carbohydrazones and their use as catalyst precursors in oxidation of cyclohexane

D Dragancea, N Talmaci, S Shova, G Novitchi… - Inorganic …, 2016 - ACS Publications
Six dinuclear vanadium (V) complexes have been synthesized: NH4 [(VO2) 2 (HLH)](NH4
[1]), NH4 [(VO2) 2 (t-BuLH)](NH4 [2]), NH4 [(VO2) 2 (ClLH)](NH4 [3]),[(VO2)(VO)(HLH) …

Novel scorpionate and pyrazole dioxovanadium complexes, catalysts for carboxylation and peroxidative oxidation of alkanes

TFS Silva, KV Luzyanin, MV Kirillova… - Advanced Synthesis …, 2010 - Wiley Online Library
The dioxovanadium (V) complexes [VO2 (3, 5‐Me2Hpz) 3][BF4](1)(pz= pyrazolyl),[VO2
{SO3C (pz) 3}](2),[VO2 {HB (3, 5‐Me2pz) 3}](3) and [VO2 {HC (pz) 3}][BF4](4), bearing …

Tetranuclear copper (II)–Schiff-base complexes as active catalysts for oxidation of cyclohexane and toluene

P Roy, M Manassero - Dalton Transactions, 2010 - pubs.rsc.org
Three new Cu (II) complexes,[Cu4 (O)(Ln) 2 (CH3COO) 4] where HL1= 4-methyl-2, 6-bis (2-
fluoroethyliminomethyl) phenol for complex 1, HL2= 4-methyl-2, 6-bis (2 …

Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

MP De Almeida, L Martins, SAC Carabineiro… - Catalysis Science & …, 2013 - pubs.rsc.org
Gold (III) complexes of type [AuCl2 {η2-RC (R′ pz) 3}] Cl [R= R′= H (1), R= CH2OH, R′=
H (2) and R= H, R′= 3, 5-Me2 (3), pz= pyrazol-1-yl] were supported on carbon materials …

Application of transition metal fluorides in catalysis

AA Tsygankov, AS Kozlov, S Liao, D Chusov - Coordination Chemistry …, 2024 - Elsevier
Transition metal (TM)-based catalysts are indispensable tools in modern organic synthesis.
Although many efficient catalysts based on TMs are already known, further improvement of …

Cu-Catalyzed C(sp3)–H Bond Activation Reaction for Direct Preparation of Cycloallyl Esters from Cycloalkanes and Aromatic Aldehydes

J Zhao, H Fang, J Han, Y Pan - Organic Letters, 2014 - ACS Publications
Cu-catalyzed dehydrogenation–olefination and esterification of C (sp3)–H bonds of
cycloalkanes with TBHP as an oxidant has been developed. The reaction involves four C–H …