A series of boron based Lewis acids have been reported to date, but among them, tris
(pentafluorophenyl) borane (BCF) has gained the most significant attention in the synthetic …

Cheminformatics-based machine learning (ML) has been employed to determine optimal
reaction conditions, including catalyst structures, in the field of synthetic chemistry. However …

Covalent organic frameworks (COFs) have emerged as a fascinating crystalline porous
material and are widely used in the field of catalysis. However, develo** simple …

The particular nature of boron compounds allows an ample modularity of their properties
ranging from Lewis acids, C‐nucleophiles, B‐nucleophiles, or even conjunctive reagents for …

The structure of solvent molecules within zeolite pores influences the rates and selectivities
of catalytic reactions by altering the free energies of reactive species. Here, we examine the …

Using D2O as a deuterium source, a method for the deuteration of intra-and extra-cyclic
methylene has been developed for cyclic ethers with moderate yield and excellent …

SU‐101 was screened for the acid‐catalyzed ring‐opening alcoholysis of cyclohexene
oxide. Results indicated access to open metal sites within SU‐101, a fundamental …

Rates and selectivities for liquid-phase reactions depend on the structure and acidity of
active sites within zeolite catalysts and the solvent environment surrounding the active sites …

The selective isomerization of strained heterocyclic compounds is an important tool in
organic synthesis. An unprecedented regioselective isomerization of 2, 2‐disubstituted …

Alcoholysis of propylene oxide (PO) is achieved over azolate ionic liquids (IL, eg, 1-
hydroxyethyl-3-methyl imidazolium imidazolate) at room temperature, accessing glycol …