Molecular chromophore–catalyst assemblies for solar fuel applications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
Finding the way to solar fuels with dye-sensitized photoelectrosynthesis cells
The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap,
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …
Direct evidence for a sequential electron transfer–proton transfer mechanism in the PCET reduction of a metal hydroxide catalyst
The proton-coupled electron transfer (PCET) mechanism for the reaction Mox–OH+ e–+
H+→ Mred–OH2 was determined through the kinetic resolution of the independent electron …
H+→ Mred–OH2 was determined through the kinetic resolution of the independent electron …
General Kinetic Model for pH Dependence of Proton-Coupled Electron Transfer: Application to an Electrochemical Water Oxidation System
The pH dependence of proton-coupled electron transfer (PCET) reactions, which are critical
to many chemical and biological processes, is a powerful probe for elucidating their …
to many chemical and biological processes, is a powerful probe for elucidating their …
The Key RuV=O Intermediate of Site-Isolated Mononuclear Water Oxidation Catalyst Detected by in Situ X-ray Absorption Spectroscopy
Improvement of the oxygen evolution reaction (OER) is a challenging step toward the
development of sustainable energy technologies. Enhancing the OER rate and efficiency …
development of sustainable energy technologies. Enhancing the OER rate and efficiency …
Photoelectrochemical approaches for the conversion of lignin at room temperature
The selective cleavage of C–C/C–O linkages represents a key step toward achieving the
chemical conversion of biomass to targeted value-added chemical products under ambient …
chemical conversion of biomass to targeted value-added chemical products under ambient …
Kinetic evidence that the solvent barrier for electron transfer is absent in the electric double layer
Classical capacitance studies have revealed that the first layer of water present at an
aqueous metal–electrolyte interface has a dielectric constant less than 1/10th of that of bulk …
aqueous metal–electrolyte interface has a dielectric constant less than 1/10th of that of bulk …
Electron transfer reorganization energies in the electrode–electrolyte double layer
The total reorganization energy, λ, for interfacial electron transfer, ET, from a conductive
electrode to redox-active molecules at fixed positions within the electric double layer, EDL …
electrode to redox-active molecules at fixed positions within the electric double layer, EDL …
Reorganization Energies for Interfacial Proton-Coupled Electron Transfer to a Water Oxidation Catalyst
The reorganization energy (λ) for interfacial electron transfer (ET) and proton-coupled ET
(PCET) from a conductive metal oxide (In2O3: Sn, ITO) to a surface-bound water oxidation …
(PCET) from a conductive metal oxide (In2O3: Sn, ITO) to a surface-bound water oxidation …
Disentangling the Physical Processes Responsible for the Kinetic Complexity in Interfacial Electron Transfer of Excited Ru(II) Polypyridyl Dyes on TiO2
Interfacial electron transfer at titanium dioxide (TiO2) is investigated for a series of surface
bound ruthenium-polypyridyl dyes whose metal-to-ligand charge-transfer state (MLCT) …
bound ruthenium-polypyridyl dyes whose metal-to-ligand charge-transfer state (MLCT) …