Gold (I)-catalyzed activation of alkynes for the construction of molecular complexity
For centuries, gold had been considered a precious, purely decorative inert metal. It was not
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous …
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous …
Optimization of catalysts and conditions in gold (I) catalysis—counterion and additive effects
Gold catalysis has proven to be an important breakthrough for organic synthesis. The
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …
Recent advances in enantioselective gold catalysis
W Zi, FD Toste - Chemical Society Reviews, 2016 - pubs.rsc.org
Interest in homogeneous gold catalysis has undergone a marked increase. As strong yet air-
and moisture-tolerant π-acids, cationic gold (I) complexes have been shown to catalyze …
and moisture-tolerant π-acids, cationic gold (I) complexes have been shown to catalyze …
Main avenues in gold coordination chemistry
In this contribution, we provide an overview of the main avenues that have emerged in gold
coordination chemistry during the last years. The unique properties of gold have motivated …
coordination chemistry during the last years. The unique properties of gold have motivated …
Tethered counterion-directed catalysis: merging the chiral ion-pairing and bifunctional ligand strategies in enantioselective gold (I) catalysis
Z Zhang, V Smal, P Retailleau, A Voituriez… - Journal of the …, 2020 - ACS Publications
Tethering a metal complex to its phosphate counterion via a phosphine ligand enables a
new strategy in asymmetric counteranion-directed catalysis (ACDC). A straightforward …
new strategy in asymmetric counteranion-directed catalysis (ACDC). A straightforward …
Addition and correction to complete field guide to asymmetric BINOL-phosphate derived Brønsted acid and metal catalysis: History and classification by mode of …
D Parmar, E Sugiono, S Raja, M Rue** - Chemical Reviews, 2017 - ACS Publications
Figure 73: The proposed catalyst/substrate interaction shown in Figure 73 corresponds to
the related sulfoxidation catalyzed by chiral phosphoric acid PA 5 (ref 133). Please note that …
the related sulfoxidation catalyzed by chiral phosphoric acid PA 5 (ref 133). Please note that …
Enantioselective Au (I)-catalyzed multicomponent annulations via tethered counterion-directed catalysis
Gold (I) complexes of a chiral phosphoric acid-functionalized phosphine of the CPA-Phos
series enable the enantioselective multicomponent reactions between aldehydes …
series enable the enantioselective multicomponent reactions between aldehydes …
Enantioselective cooperative catalysis
In recent years, enantioselective cooperative catalytic reactions, wherein two catalysts work
simultaneously to form products which cannot be obtained by the use of a single catalyst …
simultaneously to form products which cannot be obtained by the use of a single catalyst …
Recent advances in gold-complex and chiral organocatalyst cooperative catalysis for asymmetric alkyne functionalization
Homogeneous gold catalysis has demonstrated the preponderant capability of realizing a
broad range of synthetically versatile alkyne functionalization over the last two decades …
broad range of synthetically versatile alkyne functionalization over the last two decades …
Enantioselective C− H functionalization reactions under gold catalysis
Transition metal‐catalyzed enantioselective functionalization of ubiquitous C− H bonds has
proven to be promising field as it offers the construction of chiral molecular complexity in a …
proven to be promising field as it offers the construction of chiral molecular complexity in a …