Phosphorescence versus thermally activated delayed fluorescence. Controlling singlet–triplet splitting in brightly emitting and sublimable Cu (I) compounds

MJ Leitl, VA Krylova, PI Djurovich… - Journal of the …, 2014 - ACS Publications
Photophysical properties of two highly emissive three-coordinate Cu (I) complexes,(IPr) Cu
(py2-BMe2)(1) and (Bzl-3, 5Me) Cu (py2-BMe2)(2), with two different N-heterocyclic (NHC) …

Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes

WTM Seo, EY Tsui - Comments on Inorganic Chemistry, 2024 - Taylor & Francis
The interactions between transition metals and sulfur have long been studied for potential
applications in catalysis and energy storage and due to the relevance of these motifs in …

Photocatalytic carbon disulfide production via charge transfer quenching of quantum dots

CM Bernt, PT Burks, AW DeMartino… - Journal of the …, 2014 - ACS Publications
Carbon disulfide, a potentially therapeutic small molecule, is generated via oxidative
cleavage of 1, 1-dithiooxalate (DTO) photosensitized by CdSe quantum dots (QDs) …

New emissive mononuclear copper (I) complex: Structural and photophysical characterization focusing on solvatochromism, rigidochromism and oxygen sensing in …

LP Ravaro, AC Mafud, Z Li, E Reinheimer, CA Simone… - Dyes and …, 2018 - Elsevier
We report the structural and photophysical property analyses of a new emissive copper (I)
complex CuI (PPh 3)(L)(1, L= 4, 4′-dimethoxy-2, 2′-bipyridine) which demonstrates …

Synthesis of new copper (i) based linear 1-D-coordination polymers with neutral imidazolinium-dithiocarboxylate ligands

A Neuba, J Ortmeyer, DD Konieczna, G Weigel… - RSC Advances, 2015 - pubs.rsc.org
An imidazolinium-dithiocarboxylate betaine has been applied for the first time as a ligand in
a coordination polymer with copper (I) halides. The resulting 1-D-coordination compounds …

Substituent effects on the UV–visible spectrum and excited electronic states of dithiocarboxylates

AK Newman, AM Henry, JP Madriaga… - Photochemical & …, 2022 - Springer
The absorption spectra of a series of dithiocarboxylates were investigated in the ultraviolet–
visible region. Two questions that this study aimed to address were as follows:(1) What …

Synthesis and Characterization of a Stable Copper (I) Complex for Radiopharmaceutical Applications

E Bodio, M Boujtita, K Julienne, P Le Saec… - …, 2014 - Wiley Online Library
A highly stable copper (I) complex was obtained starting from a copper (II) salt. This
compound was characterized by a combination of several analytical techniques (UV/Vis …

N-Doped carbon hybrid conjugates as vectors for photocatalytic CS2 production

T Jiang, G Jiang, L Li, H Chen, H Zhou… - Materials Research …, 2015 - iopscience.iop.org
Nanostructured carbon materials have attracted much attention, because the do** or
modification can efficiently induce charge delocalization and tune the work function of …

Dimethylcuprate-mediated transformation of acetate to dithioacetate

J Li, GN Khairallah, RAJ O'Hair - Organometallics, 2015 - ACS Publications
Dithiocarboxylic acids, RCS2H, and their esters, RCS2R′, are useful reagents that can be
synthesized by the reaction of carbon disulfide with organometallic reagents. Here the …

O-Alkylthiooxalato and dithiocarboxylato complexes of molybdenum and tungsten

M El-Khateeb, HA Futouh, K Asali, H Görls, W Weigand - Polyhedron, 2012 - Elsevier
The hydrosulfido complexes CpM (CO) 3SH (M= Mo, W) react with one equivalent of O-alkyl
oxalyl chlorides, RO2CCOCl, to form the corresponding O-alkylthiooxalato complexes CpM …