Confinement effects on phase behavior of soft matter systems

K Binder, J Horbach, R Vink, A De Virgiliis - Soft Matter, 2008 - pubs.rsc.org
When systems that can undergo phase separation between two coexisting phases in the
bulk are confined in thin film geometry between parallel walls, the phase behavior can be …

Polymers at interfaces and the interactions in colloidal dispersions

A Vrij - Pure and Applied Chemistry, 1976 - degruyter.com
Solutions of different polymers in the same solvent are incompatible as a rule and show
phase separation when they are mixed. H incompatibility is also to be observed in systems …

Colloidal dispersions in external fields: recent developments

H Löwen - Journal of Physics: Condensed Matter, 2008 - iopscience.iop.org
The past five years have witnessed considerable progress in the field of colloid physics, in
particular when colloidal dispersions are exposed to external fields such as shear flow …

Perspective: The Asakura Oosawa model: A colloid prototype for bulk and interfacial phase behavior

K Binder, P Virnau, A Statt - The Journal of chemical physics, 2014 - pubs.aip.org
In many colloidal suspensions, the micrometer-sized particles behave like hard spheres, but
when non-adsorbing polymers are added to the solution a depletion attraction (of entropic …

Computation of interfacial properties via grand canonical transition matrix Monte Carlo simulation

EM Grzelak, JR Errington - The Journal of chemical physics, 2008 - pubs.aip.org
We examine two free-energy-based methods for studying the wetting properties of a fluid in
contact with a solid substrate. Application of the first approach involves examination of the …

Confinement-induced alternating interactions between inclusions in an active fluid

M Zarif, A Naji - Physical Review E, 2020 - APS
In a system of colloidal inclusions suspended in an equilibrium bath of smaller particles, the
particulate bath engenders effective, short-ranged, primarily attractive interactions between …

Crowding of polymer coils and demixing in nanoparticle–polymer mixtures

B Lu, AR Denton - Journal of Physics: Condensed Matter, 2011 - iopscience.iop.org
Abstract The Asakura–Oosawa–Vrij (AOV) model of colloid–polymer mixtures idealises
nonadsorbing polymers as effective spheres that are fixed in size and impenetrable to hard …

Colloid–polymer mixtures in random porous media: finite size scaling and connected versusdisconnected susceptibilities

RLC Vink, K Binder, H Löwen - Journal of Physics: Condensed …, 2008 - iopscience.iop.org
As a generic model for liquid–vapor-type transitions in random porous media, the Asakura–
Oosawa model for colloid–polymer mixtures is studied in a matrix of quenched spheres …

Effect of excluded volume interactions on the interfacial properties of colloid-polymer mixtures

A Fortini, PG Bolhuis, M Dijkstra - The Journal of chemical physics, 2008 - pubs.aip.org
We report a numerical study of equilibrium phase diagrams and interfacial properties of bulk
and confined colloid-polymer mixtures using grand canonical Monte Carlo simulations …

Colloid-polymer mixtures between asymmetric walls: Evidence for an interface localization transition

A De Virgiliis, RLC Vink, J Horbach… - Europhysics …, 2007 - iopscience.iop.org
We demonstrate via computer simulation that mixtures of colloids and polymers confined to
thin films have the ability to undergo an interface localization transition. While one wall of the …