The evolution of intra-and inter-molecular isotope equilibria in natural gases with thermal maturation

H **e, G Dong, M Formolo, M Lawson, J Liu… - … et Cosmochimica Acta, 2021 - Elsevier
Naturally occurring hydrocarbon fluids in sedimentary basins have economic, geological
and environmental significance. Connecting sedimentary basin temperature-time evolution …

Methane thermometry in deep-sea hydrothermal systems: evidence for re-ordering of doubly-substituted isotopologues during fluid cooling

J Labidi, ED Young, T Giunta, IE Kohl… - … et Cosmochimica Acta, 2020 - Elsevier
Deep-sea hydrothermal fluids are often enriched in carbon dioxide, methane, and hydrogen.
Methane effuses from metal-rich black smokers such as the Rainbow hydrothermal field, at …

Comparison of Experimental vs Theoretical Abundances of 13CH3D and 12CH2D2 for Isotopically Equilibrated Systems from 1 to 500 °C

DL Eldridge, R Korol, MK Lloyd, AC Turner… - ACS Earth and Space …, 2019 - ACS Publications
Methane is produced and consumed via numerous microbial and chemical reactions in
atmospheric, hydrothermal, and magmatic reactions. The stable isotopic composition of …

Experimental and theoretical determinations of hydrogen isotopic equilibrium in the system CH4H2H2O from 3 to 200° C

AC Turner, R Korol, DL Eldridge, M Bill… - … et Cosmochimica Acta, 2021 - Elsevier
The stable isotopic composition of methane (CH 4) is commonly used to fingerprint natural
gas origins. Over the past 50 years, there have been numerous proposals that both …

Experimental determination of hydrogen isotope exchange rates between methane and water under hydrothermal conditions

AC Turner, NJ Pester, M Bill, ME Conrad… - … et Cosmochimica Acta, 2022 - Elsevier
The hydrogen isotopic composition of methane (CH 4) is used as a fingerprint of gas origins.
Exchange of hydrogen isotopes between CH 4 and liquid water has been proposed to occur …

Application of an absolute reference frame for methane clumped-isotope analyses

Q Liu, J Li, W Jiang, Y Li, M Lin, W Liu, Y Shuai… - Chemical …, 2024 - Elsevier
Clumped-isotope analysis provides new constraints on the formation and evolution of
methane. High-resolution isotope-ratio mass spectrometry (HR-IRMS) is a sensitive, precise …

Δ13CH3D and Δ12CH2D2 signatures of methane aerobically oxidized by Methylosinus trichosporium with implications for deciphering the provenance of methane …

SJE Krause, J Liu, ED Young, T Treude - Earth and Planetary Science …, 2022 - Elsevier
Aerobic oxidation of methane (MOx) is an important biologically mediated process that
consumes methane in a wide range of environments. Here we report results of culture …

Rapid High-Sensitivity Analysis of Methane Clumped Isotopes (Δ13CH3D and Δ12CH2D2) Using Mid-Infrared Laser Spectroscopy

N Zhang, I Prokhorov, N Kueter, G Li… - Analytical …, 2025 - ACS Publications
Mid-infrared laser absorption spectroscopy enables rapid and nondestructive analysis of
methane clumped isotopes. However, current analytical methods require a sample size of …

Quantitative High-Field NMR-and Mass Spectrometry-Based Fatty Acid Sequencing Reveals Internal Structure in Ru-Catalyzed Deuteration of Docosahexaenoic Acid

DH Wang, D Vidovic, AI McKay, T Darwish… - Analytical …, 2022 - ACS Publications
Ru-based catalysis results in highly unsaturated fatty acid (HUFA) ethyl esters (EE)
deuterated to various extents. The products carry 2H (D) mainly at their bis-allylic positions …

Kilometer-scale Δ13CH3D profiles distinguish end-member mixing from methane production in deep marine sediments

E Lalk, JS Seewald, LT Bryndzia, S Ono - Organic Geochemistry, 2023 - Elsevier
Methane stored in marine sediments can form by microbial and thermal decomposition of
organic matter. Identifying the source of methane allows us to assess the potential of natural …